화학공학소재연구정보센터
Inorganic Chemistry, Vol.59, No.15, 10395-10399, 2020
Hexanuclear Zn(II)-Induced Dense pi-Stacking in a Metal-Organic Framework Featuring Long-Lasting Room Temperature Phosphorescence
A new strategy to enhance the room temperature phosphorescence performance has been developed through hexanuclear Zn(II)-cluster-induced dense pi-stacking in a metal-organic framework matrix. The synergistic effect of metal clusters and large overlap of pi-conjugated dimers facilitate the phosphorescence emission, migration, and separation of charge carriers for excellent photocatalytic activity.