화학공학소재연구정보센터
Inorganic Chemistry, Vol.59, No.18, 13671-13678, 2020
Activated Type I and Type II Process for Two-Photon Promoted ROS Generation: The Coordinated Zn Matters
The construction of novel classes of photosensitizers for efficient reactive oxygen species (ROS) generation is of great interest, yet it is a challenge. In this work, a bis(terpyridine)zinc(II) complex (namely, ZnL1) with two-photon absorption activity as an efficient ROS photogenerator was synthesized. Benefiting from the coordinated Zn, the decreased singlettriplet energy gap favors the intersystem crossing process facilitating the singlet oxygen (O-1(2)) generation via energy transfer. In addition, it makes the superoxide radical (O-2(center dot)) generation easier. This is an extremely rare study on two-photon excited ROS generation by activating type I and type II processes based on a cheaper and bioaccessible Zn complex.