화학공학소재연구정보센터
Inorganic Chemistry, Vol.59, No.22, 16635-16643, 2020
Methylation Design Strategy to Trigger a Dual Dielectric Switch and Improve the Phase Transition Temperature
Phase transitions of hybrid materials have aroused widespread concern and call for an in-depth study on its structure design, because the structure and characteristics are closely related, which promote potential applications in the field of temperature sensors, dielectric switches, and actuators. However, designing materials with multiple phase transitions and a high phase transition temperature (Tr) remains a huge challenge. In order to deal with this key hurdle, we tried to regulate the structural components and successfully synthesized [MASD](2)[CdCl4] (1, MASD = 8-methyl-5-azoniaspiro[4,5]decane), which displays multiple phase transitions occurring at 273.8 K and 395.9 K separately. The Tr has significantly increased compared with the parent compounds reported previously. As the temperature sensitivity of compound 1 is constant at different frequencies, it can be applied for detectors or sensors under frequency-independent or wide frequency conditions. Moreover, methylation design strategy evidently triggered the dual dielectric switch and improved the Tr, which opens a new path for finding and adjusting ideal materials of multiple phase transition.