화학공학소재연구정보센터
Korean Journal of Chemical Engineering, Vol.38, No.3, 461-474, March, 2021
A short review on dissolved lithium polysulfide catholytes for advanced lithium-sulfur batteries
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Lithium-sulfur battery (LSB) technology has drawn enormous attention during the last decade. Benefitting from the high theoretical specific discharge capacity (1,675mAh g-1) and energy density (2,600Wh kg-1), LSBs have proved to be a suitable candidate for electric vehicles and large-scale power grid electrical energy storage systems. However, the commercialization of LSB is hindered by various barriers, which include the high insulating nature of sulfur and its discharge products, severe polysulfide shuttling phenomenon, extreme volume expansion during charging/discharging, and poor stability of Li metal anodes. Additionally, LSB technology faces considerable battery design challenges, which allows high sulfur content and/or sulfur-loading while simultaneously maintaining a low electrolyte/ sulfur ratio. Therefore, in this review, we highlight recent effective strategies that lead to more practical and commercial LSBs. We restrict ourselves to various cathode architectures designed specifically to absorb dissolved polysulfide catholyte. The integration of dissolved lithium polysulfide catholyte with specially designed cathode substrates efficiently allows ultra-high sulfur loading and/or sulfur-content with low electrolyte/sulfur ratio while still exhibiting reasonable electrochemical performance and cycling stability. The effect of concentration variation of dissolved lithium polysulfide catholyte on the cell performance is also discussed in detail. Therefore, the present review encapsulates feasible strategies with practical parameters to address the problems associated with LSBs.
  1. Wadekar PH, Ghosh A, Khose RV, Pethsangave DA, Mitra S, Some S, Electrochim. Acta, 344, 136147 (2020)
  2. Li B, Pan Y, Luo B, Zao J, Xiao Y, Lei S, Cheng B, Electrochim. Acta, 344, 135811 (2020)
  3. Jiang SX, Chen MF, Wang XY, Zeng P, Li YF, Liu H, Li XL, Huang C, Shu HB, Luo ZG, Wu C, Electrochim. Acta, 313, 151 (2019)
  4. Saroha R, Gupta A, Panwar AK, J. Alloy. Compd., 696, 580 (2017)
  5. Saroha R, Panwar AK, Sharma Y, Tyagi PK, Ghosh S, Appl. Surf. Sci., 394, 25 (2017)
  6. Lee KJ, Kim TK, Koomson S, Lee CG, Korean J. Chem. Eng., 35(10), 2010 (2018)
  7. Fan L, Sun P, Yang L, Xu Z, Han J, Korean J. Chem. Eng., 37(1), 166 (2020)
  8. Ghosh S, Yong WD, Jin EM, Polaki SR, Jeong SM, Jun HB, Korean J. Chem. Eng., 36(2), 312 (2019)
  9. Ghosh S, Jeong SM, Polaki SR, Korean J. Chem. Eng., 35(7), 1389 (2018)
  10. Lee YK, Chung SC, Hwnag SY, Lee SH, Eom KS, Hong SB, Park GG, Kim BJ, Lee JJ, Joh HI, Korean J. Chem. Eng., 36(9), 1543 (2019)
  11. Zheng B, Yu L, Li N, Xi J, Electrochim. Acta, 345, 136186 (2020)
  12. Jian ZX, Li HL, Cao R, Zhou HL, Xu HZ, Zhao GJ, Xing YL, Zhang SC, Electrochim. Acta, 319, 359 (2019)
  13. Saroha R, Panwar AK, J. Phys. D-Appl. Phys., 50, 255501 (2017)
  14. Park H, Yeom DH, Kim J, Lee JK, Korean J. Chem. Eng., 32(1), 178 (2015)
  15. Venugopal N, Kim WS, Yu T, Korean J. Chem. Eng., 33(4), 1500 (2016)
  16. Kang HS, Santhoshkumar P, Park JW, Sim GS, Nanthagopal M, Lee CW, Korean J. Chem. Eng., 37(8), 1331 (2020)
  17. Xu ZL, Kim JK, Kang K, Nano Today, 19, 84 (2018)
  18. Saroha R, Panwar AK, Sharma Y, Ceram. Int., 43, 5734 (2017)
  19. Kang KM, Kim HW, Kwak HY, Korean J. Chem. Eng., 33(2), 688 (2016)
  20. Vu DL, Lee JW, Korean J. Chem. Eng., 33(2), 514 (2016)
  21. Tran QN, Kim IT, Hur JH, Kim JH, Choi HW, Park SJ, Korean J. Chem. Eng., 37(5), 898 (2020)
  22. Wang L, Wang ZY, Wu JF, Li GR, Liu S, Gao XP, Nano Energy, 77, 105173 (2020)
  23. Zhou Y, Shu H, Zhou Y, Sun T, Han M, Chen Y, Chen M, Chen Z, Yang X, Wang X, J. Power Sources, 453, 227896 (2020)
  24. Ko HS, Park HW, Kim GJ, Lee JD, Korean J. Chem. Eng., 36(4), 620 (2019)
  25. Wang ZY, Han DD, Liu S, Li GR, Yan TY, Gao XP, Electrochim. Acta, 337, 135772 (2020)
  26. Li W, Chen Z, Wang D, Gong Z, Mao C, Liu J, Peng H, Zhang Z, Li G, J. Power Sources, 435, 226778 (2019)
  27. Shi L, Zeng FL, Cheng X, Lam KH, Wang WK, Wang AB, Jin ZQ, Wu F, Yang YS, Chem. Eng. J., 334, 305 (2018)
  28. Wang J, Gao L, Gu C, Wang J, Huang J, J. Electroanal. Chem., 877, 114565 (2020)
  29. Wang H, Zhang B, Zeng X, Yan L, Zheng J, Ling M, Hou Y, Lu Y, Liang C, J. Power Sources, 473, 228588 (2020)
  30. Di Lecce D, Marangon V, Du W, Brett DJL, Shearing PR, Hassoun J, J. Power Sources, 472, 228424 (2020)
  31. Li J, Zhang L, Qin F, Hong B, Xiang Q, Zhang K, Fang J, Lai Y, J. Power Sources, 442, 227232 (2019)
  32. Tonin G, Vaughan GBM, Bouchet R, Alloin F, Di Michiel M, Barchasz C, J. Power Sources, 468, 228287 (2020)
  33. Chen S, Ming Y, Tan B, Chen S, Electrochim. Acta, 329, 135128 (2020)
  34. Zhong Y, Xu X, Liu Y, Wang W, Shao Z, Polyhedron, 155, 464 (2018)
  35. Wu T, Sun G, Lu W, Zhao L, Mauger A, Julien CM, Sun L, Xie H, Liu J, Electrochim. Acta, 353, 136529 (2020)
  36. Huang C, Sun T, Shu H, Chen M, Liang Q, Zhou Y, Gao P, Xu S, Yang X, Wu M, Jian J, Wang X, Electrochim. Acta, 334, 135658 (2020)
  37. Huang C, Zhou Y, Shu H, Chen M, Liang Q, Jiang S, Li X, Sun T, Han M, Zhou Y, Jian J, Wang X, Electrochim. Acta, 329, 135135 (2020)
  38. Wang JY, Liu YZ, Cheng M, Zhao HF, Wang J, Zhao Z, Duan XY, Wang CW, Wang JZ, Electrochim. Acta, 318, 161 (2019)
  39. Zhao Z, Li G, Wang Z, Feng M, Sun M, Xue X, Liu R, Jia H, Wang Z, Zhang W, Li H, Chen Z, J. Power Sources, 434, 226729 (2019)
  40. Zhou F, Qiao Z, Zhang Y, Xu W, Zheng H, Xie Q, Luo Q, Wang L, Qu B, Peng DL, Electrochim. Acta, 349, 136378 (2020)
  41. Kuzmina EV, Karaseva EV, Kolosnitsyn DV, Sheina LV, Shakirova NV, Kolosnitsyn VS, J. Power Sources, 400, 511 (2018)
  42. Raulo A, Bandyopadhyay S, Ahamad S, Gupta A, Srivastava R, Formanek P, Nandan B, J. Power Sources, 431, 250 (2019)
  43. Guo JW, Wu MS, Electrochim. Acta, 327, 135028 (2019)
  44. Liu S, Li Y, Zhang C, Chen X, Wang Z, Cui F, Yang X, Yue W, Electrochim. Acta, 332, 135458 (2020)
  45. Li SP, Chen X, Hu F, Zeng R, Huang YH, Yuan LX, Xie J, Electrochim. Acta, 304, 11 (2019)
  46. Lu ZW, Wang YH, Dai Z, Li XP, Zhang CY, Sun GZ, et al.,, Electrochim. Acta, 325, 134920 (2019)
  47. Kim MS, Kim MS, Do V, Xia Y, Kim W, Cho WI, J. Power Sources, 422, 104 (2019)
  48. Long J, Zhang H, Ren J, Li J, Zhu M, Han T, Sun B, Zhu S, Zhang H, Liu J, Electrochim. Acta, 356, 136853 (2020)
  49. Li W, Hicks-Garner J, Wang J, Liu J, Gross AF, Sherman E, Graetz J, Vajo JJ, Liu P, Chem. Mater., 26, 3403 (2014)
  50. Kim K, Kim PJH, Youngblood JP, Pol VG, ChemSusChem, 11, 2375 (2018)
  51. Razzaq AA, Yao Y, Shah R, Qi P, Miao L, Chen M, Zhao X, Peng Y, Deng Z, Energy Storage Mater., 16, 194 (2019)
  52. Dai S, Feng Y, Wang P, Wang H, Liang H, Wang R, Linkov V, Ji S, Electrochim. Acta, 321, 134678 (2019)
  53. Jin F, Xiao S, Lu L, Wang Y, Nano Lett., 16, 440 (2015)
  54. Li Y, Jiang T, Yang H, Lei D, Deng X, Hao C, Zhang F, Guo J, Electrochim. Acta, 330, 135311 (2020)
  55. Pei Y, Wang Y, Darraf Y, Chang AY, Zhao H, Liu X, Liu J, Lvov Y, Wang S, J. Power Sources, 450, 227698 (2020)
  56. Yao S, GuO R, Xie F, Wu Z, Gao K, Zhang C, Shen X, Li T, Qin S, Electrochim. Acta, 337, 135765 (2020)
  57. Wu Z, Yuan L, Han Q, Lan Y, Zhou Y, Jiang X, Ouyang X, Zhu J, Wang X, Fu Y, J. Power Sources, 450, 227658 (2020)
  58. Kim J, Byun D, Kim HS, Choi W, Kim SO, J. Power Sources, 427, 165 (2019)
  59. Liu B, Fang R, Xie D, Zhang W, Huang H, Xia Y, Wang X, Xia X, Tu J, Energy Environ. Mater., 1, 196 (2018)
  60. Lin DC, Liu YY, Cui Y, Nat. Nanotechnol., 12(3), 194 (2017)
  61. Liu Y, Lin D, Liang Z, Zhao J, Yan K, Cui Y, Nat. Commun., 7, 10992 (2016)
  62. Xin S, Gu L, Zhao NH, Yin YX, Zhou LJ, Guo YG, Wan LJ, J. Am. Chem. Soc., 134(45), 18510 (2012)
  63. Peng ZH, Fang WY, Zhao HB, Fang JH, Cheng HW, Doan TNL, Xu JQ, Chen P, J. Power Sources, 282, 70 (2015)
  64. Xu YH, Wen Y, Zhu YJ, Gaskell K, Cychosz KA, Eichhorn B, Xu K, Wang CS, Adv. Funct. Mater., 25(27), 4312 (2015)
  65. Rosenman A, Markevich E, Salitra G, Talyosef Y, Chesneau F, Aurbach D, J. Electrochem. Soc., 163(9), A1829 (2016)
  66. Huang JQ, Zhang Q, Wei F, Energy Storage Mater., 1, 127 (2015)
  67. Zhang ZY, Lai YQ, Zhang ZA, Zhang K, Li JE, Electrochim. Acta, 129, 55 (2014)
  68. Hao Z, Zeng R, Yuan L, Bing Q, Liu J, Xiang J, Huang Y, Nano Energy, 40, 360 (2017)
  69. Chen T, Ma L, Cheng B, Chen R, Hu Y, Zhu G, Wang Y, Liang J, Tie Z, Liu J, Nano Energy, 38, 239 (2017)
  70. Yeon JS, Park SH, Suk J, Lee H, Park HS, Chem. Eng. J., 382, 122946 (2020)
  71. Yeon JS, Yun S, Park JM, Park HS, ACS Nano, 13, 5163 (2019)
  72. Ji PH, Shang B, Peng QM, Hu XB, Wei JW, J. Power Sources, 400, 572 (2018)
  73. Chung SH, Manthiram A, Adv. Mater., 30, 170595 (2018)
  74. Wu J, Pan Z, Dai Y, Wang T, Zhang H, Yan S, Xu J, Song K, J. Alloy. Compd., 823, 153912 (2020)
  75. Wang J, Lu L, Shi D, Tandiono R, Wang Z, Konstantinov K, Liu H, ChemPlusChem, 78, 318 (2013)
  76. Lang X, Zhao Y, Cai K, Li L, Chen D, Zhang Q, Energy Technol., 7, 190054 (2019)
  77. Chen X, Du G, Zhang M, Kalam A, Ding S, Su Q, Xu B, Al-Sehemi AG, Energy Technol., 8, 190116 (2019)
  78. Peng S, Wang C, Yang S, Wang N, Wang J, Dai S, ChemElectroChem, 6, 3291 (2019)
  79. Zhang Y, Ren J, Wang D, Zhang C, Yin F, Mukanova A, Bakenov Z, ChemElectroChem, 5, 1591 (2018)
  80. Peng HJ, Huang JQ, Cheng XB, Zhang Q, Adv. Eng. Mater., 5, 150040 (2015)
  81. Yu R, Chung SH, Chen CH, Manthiram A, nergy Storage Mater., 18, 491 (2019)
  82. Xu R, Lu J, Amine K, Adv. Eng. Mater., 5, 150040 (2015)
  83. Chung SH, Chang CH, Manthiram A, Adv. Funct. Mater., 28, 180118 (2018)
  84. Song JX, Xu T, Gordin ML, Zhu PY, Lv DP, Jiang YB, Chen YS, Duan YH, Wang DH, Adv. Funct. Mater., 24(9), 1243 (2014)
  85. Fang R, Li G, Zhao S, Yin L, Du K, Hou P, Wang S, Cheng HM, Liu C, Li F, Nano Energy, 42, 205 (2017)
  86. Yuan Z, Peng HJ, Hou TZ, Huang JQ, Chen CM, Wang DW, Cheng XB, Wei F, Zhang Q, Nano Lett., 16, 519 (2016)
  87. Hagen M, Hanselmann D, Ahlbrecht K, Maca R, Gerber D, Tubke J, Adv. Eng. Mater., 5, 140198 (2015)
  88. Pope MA, Aksay IA, Adv. Eng. Mater., 5, 150012 (2015)
  89. Eroglu D, Zavadil KR, Gallagher KG, J. Electrochem. Soc., 162(6), A982 (2015)
  90. Chu MY, De Jonghe LC, Visco SJ, Katz BD, Google Patents, 6,030,720 (2000).
  91. Fu Y, Su YS, Manthiram A, Angew. Chem.-Int. Edit., 52, 6930 (2013)
  92. Pu X, Yang G, Yu C, Adv. Mater., 26(44), 7456 (2014)
  93. Liu X, Zhang Q, Huang J, Zhang S, Peng H, Wei F, J. Energy Chem., 22, 341 (2013)
  94. Fu Y, Su YS, Manthiram A, Angew. Chem.-Int. Edit., 125, 7068 (2013)
  95. Zuo Y, Zhu Y, Tang X, Zhao M, Ren P, Su W, Tang Y, Chen Y, J. Power Sources, 464, 228181 (2020)
  96. Jin L, Ni J, Shen C, Peng F, Wu Q, Ye D, Zheng J, Li G, Zhang C, Li Z, Zheng JP, J. Power Sources, 448, 227336 (2020)
  97. Liu X, Chen P, Chen J, Zeng Q, Wang Z, Li Z, Zhang L, Electrochim. Acta, 330, 135337 (2020)
  98. Lim WG, Jo CS, Lee JW, Hwang DS, Korean J. Chem. Eng., 35(2), 579 (2018)
  99. Seh ZW, Sun Y, Zhang Q, Cui Y, Chem. Soc. Rev., 45, 5605 (2016)
  100. Yeon SH, Ahn W, Shin KH, Jin CS, Jung KN, Jeon JD, Lim S, Kim Y, Korean J. Chem. Eng., 32(5), 867 (2015)
  101. Danuta H, Juliusz U, Google Patents, 3,043,896 (1962).
  102. Cunningham P, Johnson S, Cairns E, J. Electrochem. Soc., 119, 1448 (1972)
  103. Ji XL, Lee KT, Nazar LF, Nat. Mater., 8(6), 500 (2009)
  104. Ma L, Hendrickson KE, Wei SY, Archer LA, Nano Today, 10(3), 315 (2015)
  105. Xu GL, Wang Q, Fang JC, Xu YF, Li JT, Huang L, Sun SG, J. Mater. Chem. A, 2, 19941 (2014)
  106. Chung SH, Manthiram A, Adv. Funct. Mater., 24(33), 5299 (2014)
  107. Ming J, Li M, Kumar P, Li LJ, ACS Nano, 10, 6037 (2016)
  108. Yan B, Li XF, Bai ZM, Song XS, Xiong DB, Zhao ML, Li DJ, Lu SG, J. Power Sources, 338, 34 (2017)
  109. Fang X, Peng H, Small, 11, 1488 (2015)
  110. Zheng D, Wang G, Liu D, Si J, Ding T, Qu D, Yang X, Qu D, Adv. Mater. Technol., 3, 170023 (2018)
  111. Zhou L, Danilov DL, Eichel RA, Notten PH, Adv. Eng. Mater., 10, 200130 (2020)
  112. Rauh R, Abraham K, Pearson G, Surprenant J, Brummer S, J. Electrochem. Soc., 126, 523 (1979)
  113. Vijayakumar M, Govind N, Walter E, Burton SD, Shukla A, Devaraj A, Xiao J, Liu J, Wang C, Karim A, Phys. Chem. Chem. Phys., 16, 10923 (2014)
  114. Lin H, Yang DD, Lou N, Wang AL, Zhu SG, Li HZ, J. Appl. Phys., 125, 094303 (2019)
  115. Rao D, Zhang L, Wang Y, Meng Z, Qian X, Liu J, Shen X, Qiao G, Lu R, J. Phys. Chem. C, 121, 11047 (2017)
  116. Zhao YM, Zhao JX, Appl. Surf. Sci., 412, 591 (2017)
  117. Sim ES, Yi GS, Je MY, Lee YB, Chung YC, J. Power Sources, 342, 64 (2017)
  118. Wang Q, Zheng JM, Walter E, Pan HL, Lv DP, Zuo PJ, Chen HH, Deng ZD, Liaw BY, Yu XQ, Yang XQ, Zhang JG, Liu J, Xiao J, J. Electrochem. Soc., 162(3), A474 (2015)
  119. Yu X, Manthiram A, Phys. Chem. Chem. Phys., 17, 2127 (2015)
  120. Patel MU, Demir-Cakan R, Morcrette M, Tarascon JM, Gaberscek M, Dominko R, ChemSusChem, 6, 1177 (2013)
  121. Chung SH, Chang CH, Manthiram A, ACS Nano, 10, 10462 (2016)
  122. Zhou G, Zhao Y, Zu C, Manthiram A, Nano Energy, 12, 240 (2015)
  123. Zhou G, Paek E, Hwang GS, Manthiram A, Nat. Commun., 6, 1 (2015)
  124. Chiochan P, Kosasang S, Ma N, Duangdangchote S, Suktha P, Sawangphruk M, Carbon, 158, 244 (2020)
  125. Li S, Warzywoda J, Wang S, Ren G, Fan Z, Carbon, 124, 212 (2017)
  126. Niu S, Zhang SW, Shi R, Wang J, Wang W, Chen X, Zhang Z, Miao j, Amini A, Zhao Y, Cheng C, Energy Storage Mater., 33, 73 (2020)
  127. Chung SH, Luo L, Manthiram A, ACS Energy Lett., 3, 568 (2018)
  128. Zhou G, Zhao Y, Zu C, Manthiram A, Nano Energy, 12, 240 (2015)
  129. Chen S, Gao Y, Yu Z, Gordin ML, Song J, Wang D, Nano Energy, 31, 418 (2017)
  130. Barghamadi M, Best AS, Bhatt AI, Hollenkamp AF, Musameh M, Rees RJ, Ruther T, Energy Environ. Sci., 7, 3902 (2014)
  131. Zu C, Fu Y, Manthiram A, J. Mater. Chem. A, 1, 10362 (2013)
  132. Talian SD, Bobnar J, Moskon J, Dominko R, Gaberscek M, Electrochim. Acta, 354, 136696 (2020)
  133. Kim S, Song H, Jeong Y, Carbon, 113, 371 (2017)
  134. Liatard S, Benhamouda K, Fournier A, Ramos R, Barchasz C, Dijon J, ChemComm, 51, 7749 (2015)
  135. Liatard S, Benhamouda K, Fournier A, Dijon J, Barchasz C, Electrochim. Acta, 187, 670 (2016)
  136. Qu C, Chen Y, Yang X, Zhang H, Li X, Zhang H, Nano Energy, 39, 262 (2017)
  137. Li J, Lotfi N, Landers RG, Park J, J. Electrochem. Soc., 164(4), A874 (2017)
  138. Thangavel V, Xue KH, Mammeri Y, Quiroga M, Mastouri A, Guery C, Johansson P, Morcrette M, Franco AA, J. Electrochem. Soc., 163(13), A2817 (2016)
  139. Eroglu D, Zavadil KR, Gallagher KG, J. Electrochem. Soc., 162(6), A982 (2015)
  140. Mikhaylik YV, Akridge JR, J. Electrochem. Soc., 151(11), A1969 (2004)
  141. McCloskey BD, J. Phys. Chem. Lett., 6, 4581 (2015)
  142. Li YY, Yao SS, Zhang CJ, He YP, Wang YQ, Liang YZ, Shen XQ, Li TB, Qin SB, Wen W, Int. J. Energy Res., 44(11), 8388 (2020)
  143. Qie L, Zu C, Manthiram A, Adv. Eng. Mater., 6, 150245 (2016)
  144. Fang R, Zhao S, Sun Z, Wang DW, Cheng HM, Li F, Adv. Mater., 29, 160682 (2017)
  145. Scheers J, Fantini S, Johansson P, J. Power Sources, 255, 204 (2014)
  146. Zheng JM, Lv DP, Gu M, Wang CM, Zhang JG, Liu J, Xiao J, J. Electrochem. Soc., 160(11), A2288 (2013)
  147. Chung SH, Manthiram A, ACS Appl. Mater. Interfaces, 10, 43749 (2018)
  148. Jana M, Xu R, Cheng XB, Yeon JS, Park JM, Huang JQ, Zhang Q, Park HS, Energy Environ. Sci., 13, 1049 (2020)
  149. Yu R, Chung SH, Chen CH, Manthiram A, J. Mater. Chem. A, 6, 24841 (2018)
  150. Chen Y, Liu S, Yuan X, Hu X, Ye W, Razzaq AA, Lian Y, Chen M, Zhao X, Peng Y, Choi JH, Ahn JH, Deng Z, Carbon, 167, 446 (2020)
  151. Liatard S, Benhamouda K, Fournier A, Dijon J, Barchasz C, Electrochim. Acta, 187, 670 (2016)