Journal of Industrial and Engineering Chemistry, Vol.93, 448-460, January, 2021
Synergy of ionic liquid and confinement in the design of supported palladium catalyst for efficient selective hydrogenation of acetylene
E-mail:
We present here a novel fabrication of highly effective supported Pd catalysts (Pd@S-1@IL) derived from Pd@S-1 core-shell material coated with ionic liquids (ILs), [Prmim][Cl], for the selective hydrogenation of acetylene. Catalytic testing on Pd@S-1@IL catalyst illustrated a remarkable selectivity towards semi-hydrogenation (over 90% for ethylene, irrespective of conversion level). Moreover, no indications of deactivation were observed after 800 h on stream even under relatively severe conditions. Detailed characterization indicated that the selectivity enhancement was ascribed to the filter effect along with electronic effect on the adsorption/desorption processes arising from the ionic liquids layer. The stability, which has ranked the top reported values over advanced Pd-based catalysts, is attributed to the confinement effect of Pd NPs within the supports thus restricting the migration of metals. The fabrication of core-shell architecture combined with the advantages of ionic liquid layer offers a promising guideline for efficient catalytic transfer of chemical resource.
- Henley EJ, Seader JD, Roper DK, Separation Process Principles, third ed., John Wiley & Sons, 2011.
- Studt F, Abild-Pedersen F, Bligaard T, Sørensen RZ, Christensen CH, Nørskov JK, Science, 320, 1320 (2008)
- Hu TL, Wang H, Li B, Krishana R, Wu H, Zhou W, Zhao Y, Han Y, Wang X, Zhu W, Yao Z, Xiang S, Chen B, Nat. Commun., 6, 7328 (2015)
- Liu YN, McCue AJ, Miao CL, Feng JT, Li DQ, Anderson JA, J. Catal., 364, 406 (2018)
- Zhao L, Wei Z, Zhu M, Dai B, J. Ind. Eng. Chem., 25, 45 (2012)
- Zhou HR, Yang XF, Li L, Liu XY, Huang YQ, Pan XL, Wang AQ, Li J, Zhang T, ACS Catal., 6, 1054 (2016)
- Um JE, Yoon WJ, Choi HW, Kim WJ, J. Ind. Eng. Chem., 20(6), 4183 (2014)
- Gulyaeva YK, Kaichev VV, Zaikovskii VI, Suknev AP, Bal'zhinimaev BS, Appl. Catal. A: Gen., 506, 197 (2015)
- McCue AJ, Guerrero-Ruiz A, Rodriguez-Ramos I, Anderson JA, J. Catal., 340, 10 (2016)
- McCue AJ, Guerrero-Ruiz A, Ramirez-Barria C, Rodriguez-Ramos I, Anderson JA, J. Catal., 355, 40 (2017)
- Chan C, Mahadi A, Li M, Corbos E, Tang C, Jones G, Kuo W, Cookson J, Brown C, Bishop P, Tsang S, Nat. Commun., 5, 5787 (2014)
- Liu YN, Mccue AJ, Feng JT, Guan SL, Li DQ, Anderson JA, J. Catal., 364, 204 (2018)
- Alves JA, Bressa SP, Martınez OM, Barreto GF, J. Ind. Eng. Chem., 18(4), 1353 (2012)
- Glyzdova DV, Vedyagin AA, Tsapina AM, Kaichev VV, Trigub AL, Trenikhin MV, Shlyapin DA, Tsyrulnikov PG, Lavrenov AV, Appl. Catal. A: Gen., 563, 18 (2018)
- Ding L, Yi H, Zhang W, You R, Cao T, Yang J, Lu J, Huang W, ACS Catal., 6, 3700 (2016)
- Dai X, Chen Z, Yao T, Zheng L, Lin Y, Liu W, Ju H, Zhu J, Hong X, Wei S, Wu Y, Li YD, Chem. Commun., 53, 11568 (2017)
- Gulyaeva YK, Kaichev VV, Zaikovskii VI, Kovalyov EV, Suknev AP, Bal'zhinimaev BS, Catal. Today, 245, 139 (2015)
- Hou RJ, Lan XC, Wang TF, Catal. Today, 251, 47 (2015)
- Lee JH, Sudhager P, Cho YH, Kang SW, J. Ind. Eng. Chem., 74, 103 (2019)
- Bera A, Agarwal J, Shah M, Shah S, Vij RK, J. Ind. Eng. Chem., 82, 17 (2020)
- Palgunadi J, Kim HS, Lee JM, Jung S, Chem. Eng. Process., 49(2), 192 (2010)
- Zhao X, Xing HB, Yang QW, Li RL, Su BG, Bao ZB, Yang YW, Ren QL, J. Phys. Chem. B, 116(13), 3944 (2012)
- Zhao X, Yang QW, Xu D, Bao ZB, Zhang Y, Su BG, Ren QL, Xing HB, AIChE J., 61(6), 2016 (2015)
- Schneider MJ, Lijewski M, Woelfel R, Haumann M, Wasserscheid P, Angew. Chem.-Int. Edit., 52, 6996 (2013)
- Zhao J, Yue YX, Sheng GF, Wang BL, Lai HX, Di SX, Zhai YY, Guo LL, Li XN, Chem. Eng. J., 360, 38 (2019)
- Arras J, Steffan M, Shayeghi Y, Claus P, Chem. Commun., 4058 (2008).
- Herrmann T, Roessmann L, Lucas M, Claus P, Chem. Commun., 47, 12310 (2011)
- Wang Q, Han W, Lyu J, Zhang Q, Guo L, Li X, Catal. Sci. Technol., 7, 6140 (2017)
- Wang N, Sun QM, Bai RS, Li X, Guo GQ, Yu JH, J. Am. Chem. Soc., 138(24), 7484 (2016)
- Galadima A, Muraza O, J. Ind. Eng. Chem., 61, 265 (2018)
- Otto T, Ramallo-Lopez JM, Giovanetti LJ, Requejo FG, Zones SI, Iglesia E, J. Catal., 342, 125 (2016)
- Xu YQ, Jiang YS, Xu H, Wang QT, Huang WM, He HH, Zhai YY, Di SX, Guo LL, Xu XL, Zhao J, Feng F, Zhang QF, Li XN, Appl. Catal. A: Gen., 567, 12 (2018)
- Wang QT, Han WW, Hu HL, Lyu JH, Xu XL, Zhang QF, Wang HJ, Li XN, Chin. J. Chem. Eng., 25(12), 1777 (2017)
- Palomar J, Lemus J, Gilarranz MA, Rodriguez JJ, Carbon, 47, 1846 (2009)
- Haumann M, Schonweiz A, Breitzke H, Buntkowsky G, Werner S, Szesni N, Chem. Eng. Technol., 35(8), 1421 (2012)
- Lemus J, Palomar J, Gilarranz MA, Rodriguez JJ, Adsorption, 17, 561 (2011)
- Zhu KK, Sun JM, Liu J, Wang LQ, Peden CHF, Nie ZM, ACS Catal., 1, 682 (2011)
- Jacobsen CJH, Madsen C, Houzvicka J, Schmidt I, Carlsson A, J. Am. Chem. Soc., 122(29), 7116 (2000)
- He C, Zhang X, Gao S, Chen J, Hao Z, J. Ind. Eng. Chem., 18(5), 1598 (2012)
- Iliopoulou EF, Stefanidis S, Triantafyllidisc KS, Lappas AA, Green Chem., 16, 662 (2014)
- Janssens TVW, J. Catal., 264(2), 130 (2009)
- Wu ZJ, Goel S, Choi M, Iglesia E, J. Catal., 311, 458 (2014)
- Song HB, Yan N, Fei ZF, Kilpin KJ, Scopelliti R, Li XH, Dyson PJ, Catal. Today, 183(1), 172 (2012)
- Liu Y, Zhang WP, Liu ZC, Xu ST, Wang YD, Xie ZK, Han XW, Bao XH, J. Phys. Chem. C, 112, 15375 (2008)
- Demarquay J, Fraissard J, Chem. Phys. Lett., 136, 314 (1987)
- Shaikhutdinov S, Heemeier M, Baumer M, Lear T, Lennon D, Oldman RJ, Jackson SD, Freund HJ, J. Catal., 200(2), 330 (2001)
- Sarkany A, Weiss AH, Guczi L, J. Catal., 98, 550 (1986)
- Jalal A, Uzun A, J. Catal., 350, 86 (2017)
- Babucci M, Fang CY, Hoffman AS, Bare SR, Gates BC, Uzun A, AAPG Bull., 7, 6969 (2017)
- Luza L, Rambor CP, Gual A, Bernardi F, Domingos JB, Grehl T, Bruner P, Dupont J, ACS Catal., 6, 6478 (2016)
- Ding S, Zhang C, Liu Y, Jiang H, Xing W, Chen R, J. Ind. Eng. Chem., 46, 258 (2017)
- Azizi Y, Petit C, Pitchon V, J. Catal., 256(2), 338 (2008)
- Umpierre AP, Machado G, Fecher GH, Morais J, Dupont J, Adv. Synth. Catal., 347, 1404 (2005)
- Zvereva EE, Katsyuba SA, Dyson PJ, Aleksandrov AV, J. Phys. Chem. C, 120, 4596 (2016)
- Katsyuba SA, Zvereva EE, Yan N, Yuan X, Kou Y, Dyson PJ, ChemphysChem, 13, 1781 (2012)
- Zhao S, Ren Y, Lu W, Wang J, Yin W, Phys. Chem. Chem. Phys., 14, 13444 (2012)
- Redel E, Walter M, Thomann R, Hussein L, Kruger M, Janiak C, Chem. Commun., 46, 1159 (2010)
- Noh G, Shi ZC, Zones SI, Iglesia E, J. Catal., 368, 389 (2018)