화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.93, 279-289, January, 2021
An investigation on the N2O decomposition activity of MnxCo1xCo2O4 nanorods prepared by the thermal decomposition of their oxalate precursors
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This investigation aimed to develop a series of new spinel-oxide catalysts with the general formula MnxCo1-xCo2O4 (0.0 ≤ x ≤ 1.0) and testing their activity towards N2O direct decomposition. These catalysts have been prepared by the microwave-assisted co-precipitation method and the subsequent calcination at 500 °C. Characterization results revealed that the utilized preparation protocol has led to the development of pure spinel phases with nanorods morphology. N2O decomposition experiments indicated that the prepared catalysts were active and the best performance was exhibited by Mn0.75Co0.25Co2O4 catalyst. The activity of the Mn0.75Co0.25Co2O4 was enhanced by doping with K-ions at optimal concentration (nK/(nCo + nMn) = 0.025). The co-existence of some contaminants (O2, NO, H2O vapor) in the reactor feed revealed different inhibitory levels on the performance of the K0.025Mn0.75Co0.25Co2O4 catalyst. The inhibitory order was O2 < H2O < NO < O2 + H2O < O2 + H2O + NO.
  1. Konsolakis M, ACS Catal., 5, 6397 (2015)
  2. Perez-Alonso FJ, Melian-Cabrera I, Granados ML, Kapteijn F, Fierro JLG, J. Catal., 239(2), 340 (2006)
  3. Zhu YY, Wang XD, Wang AQ, Wu GT, Wang JH, Zhang T, J. Catal., 283(2), 149 (2011)
  4. Huang CD, Zhu YY, Wang XD, Liu X, Wang JH, Zhang T, J. Catal., 347, 9 (2017)
  5. Wu Y, Ni X, Beaurain A, Dujardin C, Granger P, Appl. Catal. B: Environ., 125, 149 (2012)
  6. Amrousse R, Tsutsumi A, Bachar A, Lahcene D, Appl. Catal. A: Gen., 450, 253 (2013)
  7. Maniak G, Stelmachowski P, Zasada F, Piskorz W, Kotarba A, Sojka Z, Catal. Today, 176(1), 369 (2011)
  8. Zhang J, Hu H, Xu J, Wu G, Zeng Z, J. Environ. Sci., 26, 1437 (2014)
  9. Dou Z, Zhang H, Pan Y, Xu X, J. Fuel Chem. Technol., 42, 238 (2014)
  10. Abu-Zied BM, Soliman SA, Abdellah SE, Chin. J. Catal., 35, 1105 (2014)
  11. Obalova L, Karaskova K, Jiratova K, Kovanda F, Appl. Catal. B: Environ., 90(1-2), 132 (2009)
  12. Abu-Zied BM, Schwieger W, Unger A, Appl. Catal. B: Environ., 84(1-2), 277 (2008)
  13. Meng T, Ren N, Ma Z, Chin. J. Chem. Eng., 26(5), 1051 (2018)
  14. Abu-Zied BM, Schwieger W, Appl. Catal. B: Environ., 85(3-4), 120 (2009)
  15. Kim MJ, Kim HJ, Lee SJ, Ryu LS, Yoon HC, Lee KB, Jeon SG, Catal. Commun., 130, 105764 (2019)
  16. Kubonova L, Fridrichova D, Wach A, Kustrowski P, Obalova L, Cool P, Catal. Today, 257, 51 (2015)
  17. Dey S, Dhal GC, Mater. Sci. Energy Technol., 2, 575 (2019)
  18. Abu-Zied BM, Soliman SA, Abdellah SE, J. Ind. Eng. Chem., 21, 814 (2015)
  19. Abu-Zied BM, Soliman SA, Abdellah SE, Mod. Res. Catal., 6, 47 (2017)
  20. Abu-Zied BM, Chin. J. Catal., 32, 264 (2011)
  21. Yan L, Ren T, Wang X, Gao Q, Ji D, Suo J, Catal. Commun., 4, 505 (2003)
  22. Franken T, Palkovits R, Appl. Catal. B: Environ., 176-177, 298 (2015)
  23. Yan L, Ren T, Wang XL, Ji D, Suo JS, Appl. Catal. B: Environ., 45(2), 85 (2003)
  24. Ivanova YA, Sutormina EF, Isupova LA, Rogov VA, Kinet. Catal., 59, 357 (2018)
  25. Stelmachowski P, Zasada F, Maniak G, Granger P, Inger M, Wilk M, Kotarba A, Sojka Z, Catal. Lett., 130(3-4), 637 (2009)
  26. Grzybek G, Stelmachowski P, Indyka P, Inger M, Wilk M, Kotarba A, Sojka Z, Catal. Today, 257, 93 (2015)
  27. Chromcakova Z, Obalova L, Kovanda F, Legut D, Titov A, Ritz M, Fridrichova D, Michalik S, Kustrowski P, Jiratova K, Catal. Today, 257, 18 (2015)
  28. Ohnishi C, Asano K, Iwamoto S, Chikama K, Inoue M, Catal. Today, 120(2), 145 (2007)
  29. Maniak G, Stelmachowski P, Kotarba A, Sojka Z, Rico-Perez V, Bueno-Lopez A, Appl. Catal. B: Environ., 136-137, 302 (2013)
  30. Abu-Zied BM, Soliman SA, Asiri AM, Appl. Surf. Sci., 479, 148 (2019)
  31. Asano K, Ohnishi C, Iwamoto S, Shioya Y, Inoue M, Appl. Catal. B: Environ., 78(3-4), 242 (2008)
  32. Klyushina A, Pacultova K, Krejcova S, Slowik G, Jiratova K, Kovanda F, Ryczkowski J, Obalova L, Catal. Today, 257, 2 (2015)
  33. Pasha N, Lingaiah N, Babu NS, Reddy PSS, Sai Prasad PS, Catal. Commun., 10, 132 (2008)
  34. Stelmachowski P, Maniak G, Kotarba A, Sojka Z, Catal. Commun., 10, 1062 (2009)
  35. Ciura K, Grzybek G, Wojcik S, Indyka P, Kotarba A, Sojka Z, React. Kinet. Mech. Catal., 121, 645 (2017)
  36. Yu HB, Wang XP, Li Y, Catal. Today, 339, 274 (2020)
  37. Abu-Zied BM, Soliman SA, Catal. Lett., 132(3-4), 299 (2009)
  38. Obalova L, Karaskova K, Wach A, Kustrowski P, Mamulova-Kutlakova K, Michalika S, Jiratova K, Appl. Catal. A: Gen., 462-463, 227 (2013)
  39. Karaskova K, Obalova L, Jiratova K, Kovanda F, Chem. Eng. J., 160(2), 480 (2010)
  40. Pacultova K, Drastikova V, Chromcakova Z, Bilkova T, Kutlakova KM, Kotarba A, Obalova L, J. Mol. Catal. A-Chem., 428, 33 (2017)
  41. Abu-Zied BM, Bawaked SM, Kosa SA, Ali TT, Schwieger W, Aqlan FM, Appl. Surf. Sci., 419, 399 (2017)
  42. Abu-Zied BM, Bawaked SM, Kosa SA, Schwieger W, J. Nanomater. (2015).
  43. Abu-Zied BM, Bawaked SM, Kosa SA, Schwieger W, Int. J. Electrochem. Sci., 11, 2230 (2016)
  44. Abu-Zied BM, Asiri AM, Chin. J. Catal., 36, 1837 (2015)
  45. Abu-Zied BM, Bawaked SM, Kosa SA, Schwieger W, Appl. Surf. Sci., 351, 600 (2015)
  46. Liu ZY, Liu ZH, Li QH, Yang TZ, Zhang DM, Mater. Chem. Phys., 131(1-2), 102 (2011)
  47. Ren L, Wang PP, Han YS, Hu CW, Wei BQ, Chem. Phys. Lett., 476(1-3), 78 (2009)
  48. Tang W, Wu X, Li S, Li W, Chen Y, Catal. Commun., 56, 134 (2014)
  49. Wu MZ, Zhan WC, Guo YL, Guo Y, Wang YS, Wang L, Lu GZ, Appl. Catal. A: Gen., 523, 97 (2016)
  50. Dziembaj R, Zaitz MM, Rutkowska M, Molenda M, Chmielarz L, Catal. Today, 191(1), 121 (2012)
  51. Yu HB, Tursun M, Wang XP, Wu XX, Appl. Catal. B: Environ., 185, 110 (2016)
  52. Sui C, Zhang T, Dong Y, Yuan F, Niu X, Zhu Y, Mol. Catal., 435, 174 (2017)
  53. Yu HB, Wang XP, Wu XX, Chen Y, Chem. Eng. J., 334, 800 (2018)
  54. Basahel SN, Abd El-Maksod IH, Abu-Zied BM, Mokhtar M, J. Alloy. Compd., 493, 630 (2010)
  55. Klyushina A, Pacultova K, Karaskova K, Jiratova K, Ritz M, Fridrichova D, Volodarskaja A, Obalova L, J. Mol. Catal. A-Chem., 425, 237 (2016)
  56. Lykaki M, Papista E, Kaklidis N, Carabineiro SAC, Konsolakis M, Catalysts, 9, 233 (2019)
  57. Dou Z, Feng M, Xu X, J. Fuel Chem. Technol., 41, 1234 (2013)
  58. Klegova A, Inayat A, Indyka P, Grybos J, Sojka Z, Pacultova K, Schwieger W, et al., Appl. Catal. B: Environ., 255, 117745 (2019)
  59. Trivedi S, Prasad R, J. Environ. Chem. Eng., 4, 1017 (2016)
  60. Bulavchenko OA, Gerasimov EY, Afonasenko TN, Dalton Trans., 47, 17153 (2018)
  61. Chuang TJ, Brundle CR, Rice DW, Surf. Sci., 59, 413 (1976)
  62. Wang Y, Hu X, Zheng K, Wei X, Zhao Y, Catal. Commun., 111, 70 (2018)
  63. Piumetti M, Bensaid S, Russo N, Fino D, Appl. Catal. B: Environ., 165, 742 (2015)
  64. Stelmachowski P, Maniak G, Kaczmarczyk J, Zasada F, Piskorz W, Kotarba A, Sojka Z, Appl. Catal. B: Environ., 146, 105 (2014)
  65. Xue L, Zhang CB, He H, Teraoka Y, Appl. Catal. B: Environ., 75(3-4), 167 (2007)
  66. Mei J, Zhao SJ, Huang WJ, Qu Z, Yan NQ, J. Hazard. Mater., 318, 1 (2016)
  67. Zasada F, Stelmachowski P, Maniak G, Paul JF, Kotarba A, Sojka Z, Catal. Lett., 127(1-2), 126 (2009)