화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.90, 58-75, October, 2020
Optimal synthesis, characterization and antifouling performance of Pluronic F127/bentonite-based super-hydrophilic polyvinyl chloride ultrafiltration membrane for enhanced oilfield produced water treatment
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Pluronic F127 (PF127-) and PF127/bentonite-blended PVC ultrafiltration membranes are prepared in salt coagulation baths involving NaCl, KCl, NH4Cl, MgCl2 and CaCl2. Saturated KCl-coagulation bath delivers super-hydrophilic membrane with improved surface-porosity (10.64 %), pore density (49.26 μm-2), roughness (51.12 nm) and hydrophilicity (contact angle <10 ), which endows remarkable enhancement of pure water flux at 100 kPa (i.e., 1610.0 Lm-2 h-1) and antifouling performance (flux recovery ratio: 75.8 %). Membrane performance is further improved by maximizing permeate flux and oil rejection simultaneously for actual oilfield produced water treatment using PVC-, PF127- and bentonite-loading, feed pH and feed temperature as decision variables and Pareto-optimal solution is obtained.
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