화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.87, 250-263, July, 2020
Novel metal.organic framework of UTSA-16 (Zn) synthesized by a microwave method: Outstanding performance for CO2 capture with improved stability to acid gases
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Herein we present a novel metal.organic framework (UTSA-16 (Zn)), where cobalt in the framework is replaced by zinc via microwave irradiation, with significantly improved stability in humid air and acid gases and better selectivity (CO2/N2) than the original Co-containing framework. The synthesis was performed using microwave irradiation by changing the irradiation time from 1 to 6 h. The integrities of the frameworks were assessed with scanning electron microscopy for particle morphology, powder X-ray diffraction for crystal integrity, Brunauer.Emmett.Teller for structural properties, and thermogravi- metric analysis for thermal stability. An irradiation time of 4 h produced 4h-UTSA-16 with an outstanding CO2 adsorption capacity of 4.71 mmol/g at 298 K and 1 bar and with CO2/N2 selectivity of 118. The improvement in stability and CO2/N2 sorption selectivity of UTSA-16 (Zn) over the parent UTSA-16 (Co) was not compromised by decreases in CO2 uptake after exposure to humid air, SO2, and NO2 gases. Further, analysis of production cost showed that the UTSA-16 (Zn) is superior to other adsorbents for CO2 capture.
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