화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.86, 186-193, June, 2020
Preparation of melanoidin/TiO2 composites with improved UV screening ability and suppressed photocatalytic activity for cosmetic application
E-mail:
Hybridization of TiO2, which efficiently blocks UVB, with melanoidin, which blocks UVA, was performed. TiO2 microspheres were prepared using surfactant assisted sol.gel method and carboxylation on TiO2 surface was proceeded to introduce chemical binder. Then, dihydroxyacetone was grafted onto the surface of TiO2 by esterification to prepare the melanoidin/TiO2 composites through the Maillard reaction between dihydroxyacetone and Arginine. The melanoidin/TiO2 composites showed not only suppressed photocatalytic activity but also provided the broad UV absorption range from 280 to 400 nm. Furthermore, hybrid composites can reduce white cast phenomena of TiO2, suggesting more promising application of TiO2 in cosmetics.
  1. Ichihashi M, Ueda M, Budiyanto A, Bito T, Oka M, Fukunaga M, Tsuru K, Horikawa T, Toxicology, 189, 21 (2003)
  2. Matsumura Y, Ananthaswamy HN, Toxicol. Appl. Pharmacol., 195, 298 (2004)
  3. Armstrong BK, Kricker A, J. Photochem. Photobiol. B-Biol., 63, 8 (2001)
  4. Agar NS, Halliday GM, Barnetson RS, Ananthaswamy HN, Wheeler M, Jones AM, Proc. Natl. Acad. Sci. U.S.A., 101, 4954 (2004)
  5. Biniek K, Levi K, Dauskardt RH, Proc. Natl. Acad. Sci. U.S.A., 109, 17111 (2012)
  6. Wong T, Orton D, Clin. Dermatol., 29, 306 (2011)
  7. Schlumpf M, Cotton B, Conscience M, Haller V, Steinmann B, Lichtensteiger W, Environ. Health Perspect., 109, 239 (2001)
  8. Serpone N, Dondi D, Albini A, Inorg. Chim. Acta., 360, 794 (2007)
  9. Smijs TG, Pavel S, Nanotechnol. Sci. Appl., 4, 95 (2011)
  10. Dunford R, Salinaro A, Cai L, Serpone N, Horikoshi S, Hidaka H, Knowland J, Febs Lett., 418, 87 (1997)
  11. Brezova V, Gabcova S, Dvoranova D, Stasko A, J. Photochem. Photobiol. B-Biol., 79, 121 (2005)
  12. Sayes CM, Wahi R, Kurian PA, Liu Y, West JL, Ausman KD, Warheit DB, Clovin VL, Toxicol. Sci., 92, 174 (2006)
  13. Ortelli S, Poland CA, Baldi G, Costa AL, Environ. Sci.: Nano, 3, 602 (2016)
  14. Morsella M, Giammatteo M, Arrizza L, Tonucci L, Bressan M, d’Alessandro N, RSC Adv., 5, 57453 (2015)
  15. Corazzari I, Livraghi S, Ferrero S, Giamello E, Fubini B, Fenoglio I, J. Mater. Chem., 22, 19105 (2012)
  16. Xiao J, Chen WQ, Wang FYK, Du JZ, Macromolecules, 46(2), 375 (2013)
  17. Ukaji E, Furusawa T, Sato M, Suzuki N, Appl. Surf. Sci., 254(2), 563 (2007)
  18. Jang E, Sridharan K, Park YM, Park TJ, Chem. - Eur. J., 22, 12022 (2016)
  19. Li Y, Tang L, Ma X, Wang X, Zhou W, Bai D, J. Phys. Chem. Solids, 107, 62 (2017)
  20. Biswick T, Park DH, Choy JH, J. Phys. Chem. Solids, 73, 1510 (2012)
  21. Zaccariello G, Back M, Benedetti A, Canton P, Cattaruzza E, Onoda H, Glisenti A, Alimonti A, Bocca B, Riello P, J. Colloid Interface Sci., 549, 1 (2019)
  22. Zaccariello G, Back M, Zanello M, Canton P, Cattaruzza E, Riello P, Alimonti A, Benedetti A, ACS Appl. Mater. Interfaces, 9, 1913 (2017)
  23. Wawrzynczak A, Feliczak-Guzik A, Nowak I, Nanobiomaterials in Galenic Formulations and Cosmetics, William Andrew Publishing, pp.25 2016.
  24. Wang HY, Qian H, Yao WR, Food Chem., 128, 573 (2011)
  25. Hofmann T, Czerny M, Calligaris S, Schieberle P, J. Agric. Food Chem., 49, 2382 (2001)
  26. Delgado-Andrade C, Rufian-Henares JA, Morales FJ, J. Agric. Food Chem., 53, 7832 (2005)
  27. Fusaro RM, Rice EG, The Maillard Reaction for Sunlight Protection, (2005).
  28. Chen DH, Huang FZ, Cheng YB, Caruso RA, Adv. Mater., 21(21), 2206 (2009)
  29. Rajaeian B, Heitz A, Tade MO, Liu SM, J. Membr. Sci., 485, 48 (2015)
  30. Cammerer B, Kroh LW, Food Chem., 53, 55 (1995)
  31. Pelaez M, Nolan NT, Pillai SC, Seery MK, Falaras P, Kontos AG, Dunlop PSM, Hamilton JWJ, Byrne JA, O'Shea K, Entezari MH, Dionysiou DD, Appl. Catal. B: Environ., 125, 331 (2012)
  32. Sridharan K, Park TJ, Appl. Catal. B: Environ., 134-135, 174 (2013)
  33. Sridharan K, Jang E, Park TJ, CrystEngComm, 15, 8241 (2013)
  34. Rahman M, Macelroy J, Dowling D, J. Nanosci. Nanotechnol., 11, 8642 (2011)
  35. Mohsin GF, Schmitt FJ, Kanzler C, Epping JD, Flemig S, Hornemann A, Food Chem., 245, 761 (2018)
  36. Echavarria A, Pagan J, Ibarz A, Sci. Agropec., 7(1) (2016)
  37. Guan XH, Chen GH, Shang C, J. Environ. Sci., 19, 438 (2007)
  38. Dwyer J, Kavanagh L, Lant P, Chemosphere, 71, 1745 (2008)
  39. Kwak EJ, Lee YS, Murata M, Homma S, LWT - Food Sci. Technol., 37, 255 (2004)