화학공학소재연구정보센터
International Journal of Hydrogen Energy, Vol.45, No.1, 798-808, 2020
Improvement in the hydrogenation-dehydrogenation performance of a Mg-Al alloy by graphene supported Ni
Mg-based materials are very promising candidates for hydrogen storage. In this paper, the graphene supported Ni was introduced to the Mg90Al10 system by hydrogenation synthesis (HS) and mechanical milling (MM). The 80 wt%Ni@Gn catalyst was synthesized by a facile chemical reduction method. The microstructures of the catalyst and composite show that Ni nanoparticles are well supported on the surface of graphene and they are dispersed uniformly on the surface of MgH2 particles. After heating to 450 degrees C and holding at 340 degrees C for 2 h subsequently under 2.0 MPa hydrogen pressure, all the samples are almost completely hydrogenated. According to the temperature programmed desorption test, the Mg90Al10-8(80 wt%Ni@Gn) composite could desorb 5.85 wt% H-2 which comes up to 96% of the theoretical hydrogen storage capacity. Moreover, it shows the optimal hydriding/dehydriding performance, absorbing 5.11 wt% hydrogen within 400 s at 523 K, and desorbing 5.81 wt% hydrogen within 1800 s at 573 K. (C) 2019 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.