화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.84, 150-166, April, 2020
Production of hydrogen-rich syngas and multiwalled carbon nanotubes by biogas decomposition over zirconia supported iron catalysts
E-mail:,
A set of Fe/ZrO2 catalysts were successfully synthesized by a facile urea-assisted solid-state combustion method, and their catalytic test was evaluated for the thermal decomposition of undiluted-biogas into hydrogen-rich syngas and multiwalled carbon nanotubes (MWCNTs). The as-prepared catalysts were characterized by X-Ray diffraction (XRD), Scanning and Transmission electron microscopy (SEM and TEM), Nitrogen-physisorption, X-ray photoelectron spectroscopy and Temperature programmed reduction analyses. The iron was found in the form of hematite and metallic-iron in the fresh and reduced catalysts respectively. A suitable metal-support interaction due to the fine surface dispersion of iron species on ZrO2 was observed in the catalysts. The N2-physisorption analysis indicated the reduced surface area of the catalysts after iron loading. However, it does not influence the catalytic efficiency since the metal amount and metal-support interaction was determined to play the main role. The Fe/ZrO2 catalysts exhibited improved catalytic efficiency. With increasing the amount of iron and increasing the reaction temperature, the CH4 and CO2 conversions were increased significantly. A highest CH4 and CO2 conversions of 92% and 89% respectively, with an H2/CO ratio of ∼2.25 were obtained for the 50%Fe/ZrO2 catalyst at 900 °C. The enhanced catalytic performance could be attributed to the fine-surface dispersion of iron-nanocrystals on ZrO2. Moreover, the MWCNTs were characterized by XRD, SEM, TEM and Raman analyses for their structural properties.
  1. Izquierdo-Colorado A, Debek R, Da Costa P, Galvez ME, Int. J. Hydrog. Energy, 43(27), 11981 (2018)
  2. Poeschl M, Ward S, Owende P, J. Clean Prod., 24, 168 (2012)
  3. Gao YC, Jiang JG, Meng Y, Yan F, Aihemaiti A, Energy Conv. Manag., 171, 133 (2018)
  4. Lau CS, Tsolakis A, Wyszynski ML, Int. J. Hydrog. Energy, 36(1), 397 (2011)
  5. Charisiou ND, Iordanidis A, Polychronopoulou K, Yentekakis IV, Goula MA, Mater. Today, 5, 27607 (2018)
  6. Sache E, Santos JL, Smith TJ, Centeno MA, Garcia HA, Odriozola JA, et al., J. CO2 Util., 25, 68 (2018)
  7. Roy PS, Song JW, Kim KS, Kim JM, Park CS, Raja ASK, J. Ind. Eng. Chem., 62, 120 (2018)
  8. Luo M, Yi Y, Wang S, Wang Z, Du M, Pan J, et al., Renew. Sust. Energ. Rev., 81, 3186 (2018)
  9. Maisano S, Urbani F, Cipiti F, Freni F, Chiodo V, Int. J. Hydrog. Energy, 44(9), 4414 (2019)
  10. Campanario FJ, Ortiz FJG, Energy Conv. Manag., 150, 599 (2017)
  11. Vakili R, Gholami R, Stere CE, Chansai S, Chen H, et al., Appl. Catal. B: Environ., 260, 118195 (2020)
  12. Moral A, Reyero I, Alfaro C, Bimbela F, Gandia LM, Catal. Today, 299, 280 (2018)
  13. Rosha P, Mohapatra SK, Mahla SK, Dhir A, Energy, 172, 733 (2019)
  14. Jang WJ, Shim JO, Kim HM, Yoo SY, Roh HS, Catal. Today, 324, 15 (2019)
  15. Li MS, van Veen AC, Appl. Catal. B: Environ., 237, 641 (2018)
  16. Charisiou ND, Douvartzides SL, Siakavelas GI, Tzounis L, Sebastian V, Stolojan V, Hinder SJ, Baker MA, Polychronopoulou K, Goula MA, Catalysts, 9, 676 (2019)
  17. Charisiou ND, Tzounis L, Sebastian V, Hinder SJ, Baker MA, Polychronopoulou K, Goula MA, Appl. Surf. Sci., 474, 42 (2019)
  18. Charisiou ND, Siakavelas G, Tzounis L, Sebastian V, Monzon A, Baker MA, Hinder SJ, Polychronopoulou K, Yentekakis IV, Goula MA, Int. J. Hydrog. Energy, 43(41), 18955 (2018)
  19. Mera G, Kroll P, Ponomarev I, Chen J, Morita K, Liesegang M, Ionescu E, Navrotsky A, Dalton Trans., 48, 11018 (2019)
  20. Yang Z, Tian J, Yin Z, Cui C, Qian W, Wei F, Carbon, 141, 467 (2019)
  21. Pinilla JL, de Llobet S, Suelves I, Utrilla R, Lazaro MJ, Moliner R, Fuel, 90(6), 2245 (2011)
  22. Pinilla JL, de Llobet S, Moliner R, Suelves I, Appl. Catal. B: Environ., 200, 255 (2017)
  23. Horlyck J, Lawrey C, Lovell EC, Amal R, Scott J, Chem. Eng. J., 325, 572 (2018)
  24. Li YD, Li DX, Wang GW, Catal. Today, 162(1), 1 (2011)
  25. Goula MA, Charisiou ND, Siakavelas G, Tzounis L, Tsiaoussis I, Panagiotopoulou P, Goula G, Yentekakis IV, Int. J. Hydrog. Energy, 42(19), 13724 (2017)
  26. Charisiou ND, Siakavelas G, Papageridis KN, Baklavaridis A, Tzounis L, Avraam DG, Goula MA, J. Nat. Gas Sci. and Engin., 31, 164 (2016)
  27. de Llobet S, Pinilla JL, Moliner R, Suelves I, Appl. Catal. B: Environ., 165, 457 (2015)
  28. de Llobet S, Pinilla JL, Moliner R, Suelves I, Fuel, 139, 71 (2015)
  29. de Llobet S, Pinilla JL, Moliner R, Suelves I, Arroyo J, Moreno F, Munoz M, Monne C, Camean I, Ramos A, Cuesta N, Garcia AB, Int. J. Hydrog. Energy, 38(35), 15084 (2013)
  30. de Llobet S, Pinilla JL, Lazaro MJ, Moliner R, Suelves I, Fuel, 111, 778 (2013)
  31. de Llobet S, Pinilla JL, Lazaro MJ, Moliner R, Suelves I, Int. J. Hydrog. Energy, 37(8), 7067 (2012)
  32. Ali B, Tasirin SM, Aminayi P, Yaakob Z, Ali NT, Noori W, Nanomaterials, 8, 1053 (2018)
  33. Kalai DY, Stangeland K, Jin Y, Tucho WM, Yu Z, Int. J. Hydrog. Energy, 43, 19438 (2018)
  34. Park JH, Yeo S, Chang TS, J CO2 Util., 26, 465 (2018)
  35. Calgaro CO, Perez-Lopez OW, Int. J. Hydrog. Energy, 44(33), 17750 (2019)
  36. Awadallah AE, Aboul-Enein AA, El-Desouki DS, Aboul-Gheit AK, Appl. Surf. Sci., 296, 100 (2014)
  37. Solis-Garcia A, Louvier-Hernandez JF, Almendarez-Camarillo A, Fierro-Gonzalez JC, Appl. Catal. B: Environ., 218, 611 (2017)
  38. Li WH, Nie XW, Jiang X, Zhang AF, Ding FS, Liu M, Liu ZM, Guo XW, Song CS, Appl. Catal. B: Environ., 220, 397 (2018)
  39. Pudukudy M, Yaakob Z, Takriff MS, Energy Conv. Manag., 126, 302 (2016)
  40. Pudukudy M, Yaakob Z, Takriff MS, Appl. Surf. Sci., 356, 1320 (2015)
  41. Charisiou ND, Papageridis KN, Tzounis L, Sebastian V, Hinder SJ, Baker MA, AlKetbi M, Polychronopoulou K, Goula MA, Int. J. Hydrog. Energy, 44(1), 256 (2019)
  42. Pudukudy M, Yaakob Z, Dahani N, Takriff MS, Hassan NSM, J Clust Sci., 28, 1579 (2017)
  43. Abbas M, Xue YY, Zhang J, Chen JG, Fuel Process. Technol., 187, 63 (2019)
  44. Guo T, Wang K, Zhang GK, Wu XY, Appl. Surf. Sci., 469, 331 (2019)
  45. Li WH, Liu Y, Mu MC, Ding FS, Liu ZM, Guo XW, Song CS, Appl. Catal. B: Environ., 254, 531 (2019)
  46. Veluya S, Suzuki K, Gopinath CS, Yoshida H, Hattori T, Phys. Chem. Chem. Phys., 4, 1990 (2002)
  47. Wang J, Shi T, Jiang X, Nanoscale Res. Lett., 4, 240 (2009)
  48. Ye C, Hu K, Niu Z, Lu Y, Zhang L, Yan K, J. Water Process Eng., 27, 205 (2019)
  49. Liu Y, Niu Z, Lu Y, Zhang L, Yan K, J. Alloy. Compd., 735, 654 (2018)
  50. Cai JJ, Li S, Qin GW, Appl. Surf. Sci., 466, 92 (2019)
  51. Chen A, Xu L, Zhang X, Yang Z, Yang S, ACS Appl. Mater. Interfaces, 8, 33765 (2016)
  52. Deng JJ, Zhuo QQ, Lv XX, J. Electroanal. Chem., 835, 287 (2019)
  53. Rastegarpanah A, Rezaei M, Meshkani F, Zhang KF, Zhao XT, Pei WB, Liu YX, Deng JG, Arandiyan H, Dai HX, Appl. Catal. B: Environ., 248, 515 (2019)
  54. Rategarpanah A, Meshkani F, Wang Y, Arandiyan H, Rezaei M, Energy Conv. Manag., 168, 268 (2018)
  55. Hakeem AA, Rajendran J, Kapteijn F, Makkee M, Catal. Today, 242, 168 (2015)
  56. Zou J, Oladipo J, Fu SL, Al-Rahbi A, Yang HP, Wu CF, Cai N, Williams P, Chen HP, Energy Conv. Manag., 171, 241 (2018)
  57. Zhang Z, Xia HQ, Dai QG, Wang XY, Appl. Catal. A: Gen., 557, 108 (2018)
  58. Ayastuy JL, Gurbani A, Gutierrez-Ortiz MA, Int. J. Hydrog. Energy, 41(43), 19546 (2016)
  59. Chang FW, Roselin LS, Ou TC, Appl. Catal. A: Gen., 334(1-2), 147 (2008)
  60. Venugopal A, Scurrell MS, Appl. Catal. A: Gen., 258(2), 241 (2004)
  61. Pojanavaraphan C, Luengnaruemitchai A, Gulari E, J. Ind. Eng. Chem., 20(3), 961 (2014)
  62. Piotrowski K, Mondal K, Lorethova H, Stonawski L, Szymanski T, Wiltowski T, Int. J. Hydrog. Energy, 30(15), 1543 (2005)
  63. Abdelkader A, Daly H, Saih Y, Morgan K, Mohamed MA, Halawy SA, Hardacre C, Int. J. Hydrog. Energy, 38(20), 8263 (2013)
  64. Suelves I, Pinilla JL, Lazaro MJ, Moliner R, Palacios JM, J. Power Sources, 192(1), 35 (2009)
  65. Nikoo MK, Amin NAS, Fuel Process. Technol., 92(3), 678 (2011)
  66. Chein RY, Fung WY, Int. J. Hydrog. Energy, 44(28), 14303 (2019)
  67. Fakeeha AH, Fakeeha MA, Khan WU, Al-Fatesh AS, J. Ind. Eng. Chem., 20(2), 549 (2014)
  68. Kalai DY, Stangeland K, Tucho WM, Jin Y, Yu Z, J CO2 Util., 33, 189 (2019)
  69. Aw MS, Drazic G, Djinovic P, Pinta A, Catal. Sci. Technol., 6, 3797 (2016)
  70. Rosha P, Mohapatra SK, Mahla SK, Dhir A, Biomass Bioenergy, 125, 70 (2019)
  71. Yan Q, Lu Y, To F, Li Y, Yu F, Catal. Sci. Technol., 5, 3270 (2015)
  72. Navarro-Puyuelo A, Reyero I, Moral A, Bimbela F, Banares MA, Gandia LM, J. Ind. Eng. Chem., 80, 217 (2019)
  73. Gaillard M, Virginie M, Khodakov AY, Catal. Today, 289, 143 (2017)
  74. Habibi N, Wang Y, Arandiyan H, Rezaei M, Int. J. Hydrog. Energy, 42(38), 24159 (2017)
  75. Ugarte P, Duran P, Lasobras J, Soler J, Menendez M, Herguido J, Int. J. Hydrog. Energy, 42(19), 13589 (2017)
  76. Das S, Ashok J, Bian Z, Dewangan N, Wai MH, Du Y, Borgna A, Hidajat K, Kawi S, Appl. Catal. B: Environ., 230, 220 (2018)
  77. Su J, Li Y, Fan B, Yu F, Li R, Microporous Mesoporous Mater., 233, 87 (2016)
  78. Shen Y, Lua AC, J. Colloid Interface Sci., 462, 48 (2016)
  79. Pudukudy M, Yaakob Z, Mazuki MZ, Takriff MS, Jahaya SS, Appl. Catal. B: Environ., 218, 298 (2017)
  80. Pudukudy M, Yaakob Z, Jia Q, Takriff MS, Appl. Surf. Sci., 467-468, 236 (2019)
  81. Sharma R, Moore E, Rez P, Treacy MMJ, Nano Lett., 9, 689 (2009)
  82. Pudukudy M, Yaakob Z, Chem. Eng. J., 262, 1009 (2015)
  83. Jabbour K, Saad A, Inaty L, Davidson A, Massiani P, El Hassan N, Int. J. Hydrog. Energy, 44(29), 14889 (2019)
  84. Sanchez S, Fabregas E, Pumera M, Phys. Chem. Chem. Phys., 11, 182 (2009)
  85. Cancado LG, Jorio A, Ferreira EHM, Stavale F, Achete CA, et al., Nano Lett., 11, 3190 (2011)
  86. Pumera M, Iwai H, J. Phys. Chem. C, 113, 4401 (2009)
  87. Pudukudy M, Yaakob Z, Takriff MS, RSC Adv., 6, 68081 (2016)
  88. Dong L, Du Y, Li JM, Wang HY, Yang Y, Li S, Tan ZY, Int. J. Hydrog. Energy, 40(31), 9670 (2015)