화학공학소재연구정보센터
Journal of Chemical Technology and Biotechnology, Vol.95, No.2, 439-449, 2020
Testing new strategies to improve the recovery of phosphorus from anaerobically digested organic fraction of municipal solid waste
BACKGROUND This work is focused on phosphorus (P) recovery from the anaerobically digested organic fraction of municipal solid waste (referred to as 'digestate') as a fertilizer. The main purpose was to propose and test modifications to the electrodialytic process that increase P extraction, improve the quality of the fertilizer by removing contaminants, and reduce hydraulic retention time to allow for smaller system footprints. Strategies tested were: (i) lowering the pH of the digestate suspension to <4.5 using the electrochemical reactions and enhance P solubilization from the waste; (ii) changing the configuration of the electrodialytic cell from three to two chambers; and (iii) stirring the sample to shorten the duration of the extraction. RESULTS Results show that the acidification of digestate by the electrochemical reactions was effective to enhance P extraction yield. Three-chamber electrodialytic experiments enabled the removal of heavy metals from the digestate, producing P-rich solutions with low metal concentrations. This resulted in the production of high-quality fertilizer which can be used for agricultural applications. The modification of the electrodialytic cell set-up from three- to two-chamber neither resulted in an increase of the P extraction yields, nor contributed to the removal of metals from the liquid phase of digestate. Reduction of the hydraulic retention time of electrodialytic extraction of P from 16 days to 9 days was attained by the use of stirring and by electrodialytic acidification. CONCLUSIONS An increase of P recovery was accomplished by modification of electrodialytic extraction, resulting in 90% of P being successfully extracted from the digestate and transformed into struvite. (c) 2019 Society of Chemical Industry