화학공학소재연구정보센터
Inorganic Chemistry, Vol.59, No.1, 308-314, 2020
In Situ Metal-Ligand Reactions under Solvent-Dependent Hydro(solvo)thermal Conditions: Structures, Mass Spectrometry, and Magnetism
In this study, four in situ hydro(solvo)thermal metal-ligand reactions, including oxidation (H2L1), C-C coupling (H4L2), nitration (H2L3), and condensation (HL (4-6)), based on bis[3-(pyridin-2-yl)-1H-1,2,4-triazol-5-yl]methane (H2L0), in the presence of Dy-III ions, were carried out. The in situ metal-ligand reaction gave six new ligands existing in eight novel Dy-III coordination complexes, which were characterized by crystal structure, mass spectrometry, and magnetism.