화학공학소재연구정보센터
Macromolecular Research, Vol.28, No.1, 51-56, January, 2020
A Selective Colorimetric Sensor for Pb2+ Detection by Using Phenylboronic Acid Functionalized Polydiacetylene Liposomes
E-mail:
Due to the high toxicity for brain and the nervous system of humans and other living organisms, the design and fabrication of a robust and sensitive method for the detection of Pb2+ in the aqueous solution has attracted the increasing attention among scientists. Herein, a colorimetric and fluorometric sensor for the detection of Pb2+ in the aqueous solution by incorporating a new phenylboronic acid functionalized polydiacetylene liposome was designed. The molar ratio of 4:1 between the monomers, 10,12-pentacosadiynoic acid (PCDA) and phenylboronic acid functionalized PCDA (PCDA-pBA) not only offered sufficient binding sites for Pb2+, but also interrupted the efficient π-conjugation backbone of polydiacetylene (PDA) chains associated with the color and fluorescence changes. Compared with other metal ions, only Pb2+ could cause the color change and the fluorescence enhancement. Moreover, the hybrid PDA liposomes exhibited high sensitivity, fast response time (10 s), and a reasonable detection limit for Pb2+ (0.1 μM). This work not only provides a versatile methodology for the fabrication of sensors for Pb2+ detection, but also is of great fundamental value for a deeper understanding of the complexion-induced color changes based on polydiacetylene materials, and may pave the way for fabrication a new method for recognizing other metal ions.
  1. Bagheri H, Afkhami A, Khoshsafar H, Rezaei M, Shirzadmehr A, Sens. Actuators B-Chem., 186, 451 (2013)
  2. Rehman AU, Ikram M, Kan K, Zhao YM, Zhang WJ, Zhang JW, Liu Y, Wang Y, Du LJ, Shi KY, Sens. Actuators B-Chem., 274, 285 (2018)
  3. Sun ZQ, Yang ZY, Zhao L, Zhang YH, Li YQ, Hou J, Ding L, New J. Chem., 43, 853 (2019)
  4. Perez-Rafols C, Serrano N, Diaz-Cruz JM, Arino C, Esteban M, Talanta, 155, 8 (2016)
  5. Xu XX, Duan GT, Li Y, Liu GQ, Wang JJ, Zhang HW, Dai ZF, Cai WP, ACS Appl. Mater. Interfaces, 6, 65 (2014)
  6. Liu Z, Luo F, Ju XJ, Xie R, Sun YM, Wang W, Chu LY, J. Mater. Chem. A, 1, 9659 (2013)
  7. Devi M, Dhir A, Pradeep CP, RSC Adv., 6, 112728 (2016)
  8. Wang D, Ge CC, Lv KP, Zou QZ, Liu Q, Liu LP, Yang QH, Ba SY, Chem. Commun., 54, 13718 (2018)
  9. Boruah BS, Biswas R, Sens. Actuators A-Phys., 276, 89 (2018)
  10. Frost MS, Dempsey MJ, Whitehead DE, Sens. Actuators B-Chem., 221, 1003 (2015)
  11. Wang Z, Xu C, Lu YX, Chen XT, Yuan H, Wei GY, Ye G, Chen J, Sens. Actuators B-Chem., 241, 1324 (2017)
  12. Sun QW, Wang JK, Tang MH, Huang LM, Zhang ZY, Liu C, Lu XH, Hunter KW, Chen GS, Anal. Chem., 89, 5024 (2017)
  13. Brown RJC, Milton MJT, Trends Anal. Chem., 24, 266 (2005)
  14. Lisak G, Ivaska A, Lewenstam A, Bobacka J, Electrochim. Acta, 140, 27 (2014)
  15. Joon NK, He N, Wagner M, Cardenas M, Bobacka J, Lisak G, Electrochim. Acta, 252, 490 (2017)
  16. Ponsa B, Carrerab A, Nein C, J. Chromatogr. B, 716, 139 (1998)
  17. Wu B, Xu L, Wang SF, Wang Y, Zhang WA, Polym. Chem., 6, 4279 (2015)
  18. Wan J, Zhang K, Li C, Li YY, Niu SY, Sens. Actuators B-Chem., 246, 696 (2017)
  19. Liao H, Liu GJ, Liu Y, Li R, Fu WS, Hu LZ, Chem. Commun., 53, 10160 (2017)
  20. Wen B, Xue JQ, Zhou XJ, Wu QW, Nie JJ, Xu JT, Du B, ACS Appl. Mater. Interfaces, 10, 25706 (2018)
  21. Hua JQ, Elioff MS, Tanlanta, 18, 552 (2018)
  22. Zhang DL, Zhu ML, Zhao LY, Zhang JH, Wang K, Qi DD, Zhou Y, Bian YZ, Jiang JZ, Inorg. Chem., 56(23), 14533 (2017)
  23. Wang DE, Wang YL, Tian C, Zhang LL, Han X, Tu Q, Yuan MS, Chen S, Wang JY, J. Mater. Chem. A, 3, 21690 (2015)
  24. Lee J, Pyo M, Lee SH, Kim J, Ra M, Kim WY, Park BJ, Lee CW, Kim JM, Nat. Commun., 5, 3736 (2014)
  25. Xu QL, Lee SY, Cho Y, Kim MH, Bouffard J, Yoon J, J. Am. Ceram. Soc., 135, 17751 (2013)
  26. Kim MJ, Angupillai S, Min K, Ramalingam M, ACS Appl. Mater. Interfaces, 10, 24767 (2018)
  27. Chen CF, Chen J, Wang TY, Liu MH, ACS Appl. Mater. Interfaces, 8, 30608 (2016)
  28. Yang G, Hu WL, Xia HY, Zou G, Zhang QJ, J. Mater. Chem. A, 2, 15560 (2014)
  29. Wang T, Guo YL, Wan PB, Sun XM, Zhang H, Yua ZZ, Chen XD, Nanoscale, 9, 869 (2017)
  30. Nie XK, Xu YT, Song ZL, Ding D, Gao F, Liang H, Chen L, Bian X, Chen Z, Tan WH, Nanoscale, 6, 13097 (2014)
  31. Li Y, Wang LH, Yin X, Ding B, Sun G, Ke T, Chen JY, Yu JY, J. Mater. Chem. A, 2, 18304 (2014)
  32. Chae S, Lee JP, Kim JM, Adv. Funct. Mater., 26(11), 1769 (2016)
  33. Park DH, Heo JM, Jeong W, Yoo YH, Park BJ, Kim JM, ACS Appl. Mater. Interfaces, 10, 5014 (2018)
  34. Pan XJ, Wang YL, Jiang H, Zou G, Zhang QJ, J. Mater. Chem., 21, 3604 (2011)