화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.81, 228-236, January, 2020
Synthesis of PANi nanoarrays anchored on 2D BiOCl nanoplates for photodegradation of Congo Red in visible light region
E-mail:
Photocatalytic processes have attained considerable attention of late years, especially for environmental remediation. Despite extensive research in this area, the need for safer, more efficient, and cost-effective processes has encouraged researchers to develop novel photocatalysis. However, the low active surface area and narrow bandgap limit their photocatalytic performances. In the present research, the 2D BiOCl sheets were successfully synthesized by a new hydrothermal method and decorated by PANi nanoarrays through in-situ oxidative polymerization of aniline. The UV-vis diffuse-reflectance and photo- luminescence spectroscopy revealed the synergistic effects between PANi nanoarrays and 2D BiOCl by enhancing the absorption in the visible light region and reduction of bandgap down to 2.9 eV. Furthermore, the morphology analysis showed the proper decoration of PANi nanoarrays on 2D BiOCl nanoplates. The synthesized nanocomposite with different weight loadings of PANi was taken to evaluate the decolorization efficiency of it. The result exhibited an optimum value of 88.35% at 60 min irradiation under visible light in the photodegradation of Congo Red (CR). Moreover, the probable photocatalytic mechanism for degradation of CR by PANi/BiCOl photocatalyst was proposed based on the scavenger experiments. The outcomes indicated that the PANi promoted the absorption intensity of the pure BiOCl in the visible region. To that, the well-arranged array and considerably high specific surface area of PANi could encourage the transfer of electrons witch generated by the photo to 2D BiOCl substrate and repel the recombination of electron-hole pairs.
  1. Hassandoost R, Pouran SR, Khataee A, Orooji Y, Joo SW, J. Hazard. Mater., 376, 200 (2019)
  2. Pirhashemi M, Habibi-Yangjeh A, Pouran SR, J. Ind. Eng. Chem., 62, 1 (2018)
  3. Tian Y, Li W, Zhao CH, Wang YF, Zhang BL, Zhang QY, Appl. Catal. B: Environ., 213, 136 (2017)
  4. Mahmoud ME, Abdou AE, Shehata AK, Header HMA, Hamed EA, J. Ind. Eng. Chem., 57, 28 (2018)
  5. Natarajan K, Bajaj HC, Tayade RJ, J. Ind. Eng. Chem., 34, 146 (2016)
  6. Kamal T, Khan SB, Asiri AM, Cellulose, 23, 1911 (2016)
  7. Pizarro AH, Catal. Commun., 90, 100 (2017)
  8. Albadarin AB, Collins MN, Naushad M, Shirazian S, Walker G, Mangwandi C, Chem. Eng. J., 307, 264 (2017)
  9. Alqadami AA, Naushad M, Alothman Z, Ahamad T, J. Environ. Manage., 223, 29 (2018)
  10. Molinari R, Pirillo F, Falco M, Loddo V, Palmisano L, Chem. Eng. Process., 43(9), 1103 (2004)
  11. Issaabadi Z, Nasrollahzadeh M, Sajadi SM, J. Clean Prod., 142, 3584 (2017)
  12. Pathania D, Sharma G, Kumar A, Naushad M, Kalia S, Sharma A, ALOthman ZA, Toxicol. Environ. Chem., 97, 526 (2015)
  13. Sharma G, Naushad M, Pathania D, Mittal A, El-Desoky G, Desalin. Water Treat., 54, 3114 (2015)
  14. Yao H, Li H, Hu T, Hou W, ChemCatChem, 10, 3726 (2018)
  15. Yoon HJ, Choi YI, Jang ES, Sohn Y, J. Ind. Eng. Chem., 32, 137 (2015)
  16. Li J, Yu Y, Zhang L, Nanoscale, 6, 8473 (2014)
  17. Zhang H, Liu L, Zhou Z, RSC Adv., 2, 9224 (2012)
  18. Ye P, Xie J, He Y, Zhang L, Wu T, Wu Y, Mater. Lett., 108, 168 (2013)
  19. Xiong JY, Cheng G, Qin F, Wang RM, Sun HZ, Chen R, Chem. Eng. J., 220, 228 (2013)
  20. Xu Y, Lin D, Liu X, Luo Y, Xue H, Huang B, Chen Q, Qian Q, ChemCatChem, 10, 2496 (2018)
  21. Wang Q, Hui J, Huang Y, Ding Y, Cai Y, Yin S, Li Z, Su B, Mater. Sci. Semicond. Process, 17, 87 (2014)
  22. Zhang X, Ai Z, Jia F, Zhang L, J. Phys. Chem. C, 112, 747 (2008)
  23. Chang X, Huang J, Cheng C, Sui Q, Sha W, Ji G, Deng S, Yu G, Catal. Commun., 11, 460 (2010)
  24. Henle J, Simon P, Frenzel A, Scholz S, Kaskel S, Chem. Mater., 19, 366 (2007)
  25. Ye L, Zan L, Tian L, Peng T, Zhang J, Chem. Commun., 47, 6951 (2011)
  26. Xu L, Wang J, Environ. Sci. Technol., 46, 10145 (2012)
  27. Li GF, Qin F, Wang RM, Xiao SQ, Sun HZ, Chen R, J. Colloid Interface Sci., 409, 43 (2013)
  28. Fan W, Zhang C, Tjiu WW, Pramoda KP, He C, Liu T, ACS Appl. Mater. Interfaces, 5, 3382 (2013)
  29. Li W, He SA, Xu W, Li J, Wang XC, Electrochim. Acta, 283, 727 (2018)
  30. Wang PQ, Bai Y, Liu JY, Fan Z, Hu YQ, Micro Nano Lett., 7, 876 (2012)
  31. Amini M, Hassandoost R, Bagherzadeh M, Gautam S, Chae KH, Catal. Commun., 85, 13 (2016)
  32. Cao J, Xu B, Lin H, Luo B, Chen S, Catal. Commun., 26, 204 (2012)
  33. Zhang L, Wang WZ, Sun SM, Sun YY, Gao EP, Xu J, Appl. Catal. B: Environ., 132, 315 (2013)
  34. Gao F, Zeng D, Huang Q, Tian S, Xie C, PCCP, 14, 10572 (2012)
  35. Ye L, Deng K, Xu F, Tian L, Peng T, Zan L, PCCP, 14, 82 (2012)
  36. Guan ML, Xiao C, Zhang J, Fan SJ, An R, Cheng QM, Xie JF, Zhou M, Ye BJ, Xie Y, J. Am. Chem. Soc., 135(28), 10411 (2013)
  37. Chatterjee MJ, Ahamed ST, Mitra M, Kulsi C, Mondal A, Banerjee D, Appl. Surf. Sci., 470, 472 (2019)
  38. Xu YG, Ma Y, Ji HY, Huang SQ, Xie M, Zhao Y, Xu H, Li HM, J. Colloid Interface Sci., 537, 101 (2019)
  39. Wang QZ, Hui J, Li JJ, Cai YX, Yin SQ, Wang FP, Su BT, Appl. Surf. Sci., 283, 577 (2013)
  40. Tanwar R, Kaur B, Mandal UK, Appl. Catal. B: Environ., 211, 305 (2017)
  41. Tanwar R, Kumar S, Mandal UK, J. Photochem. Photobiol. A-Chem., 333, 105 (2017)
  42. Mi Y, Wen L, Wang Z, Cao D, Xu R, Fang Y, Zhou Y, Lei Y, Nano Energy, 30, 109 (2016)
  43. Khataee A, Hassandoost R, Pouran SR, Ultrason. Sonochem., 41, 626 (2018)
  44. Chai SY, Kim YJ, Jung MH, Chakraborty AK, Jung D, Lee WI, J. Catal., 262(1), 144 (2009)
  45. Lei Y, Wang G, Song S, Fan W, Zhang H, CrystEngComm, 11, 1857 (2009)
  46. Tian Y, Guo CF, Guo YJ, Wang Q, Liu Q, Appl. Surf. Sci., 258(6), 1949 (2012)
  47. Liu L, Ding L, Liu YG, An WJ, Lin SL, Liang YH, Cui WQ, Appl. Catal. B: Environ., 201, 92 (2017)
  48. Wang ZM, Peng XY, Huang CY, Chen X, Dai WX, Fu XZ, Appl. Catal. B: Environ., 219, 379 (2017)
  49. Zhang F, Ding T, Zhang Y, Yang Z, Xue H, Mater. Lett., 192, 149 (2017)
  50. Tanwar R, Kaur B, Mandal UK, Appl. Catal. B: Environ., 211, 305 (2017)
  51. Shamaila S, Sajjad AKL, Chen F, Zhang JL, J. Colloid Interface Sci., 356(2), 465 (2011)
  52. Tabrizi AG, Arsalani N, Mohammadi A, Ghadimi LS, Ahadzadeh I, Namazi H, Electrochim. Acta, 265, 379 (2018)
  53. Tabrizi AG, Arsalani N, Naghshbandi Z, Ghadimi LS, Mohammadi A, Int. J. Hydrog. Energy, 43(27), 12200 (2018)
  54. Tabrizi AG, Arsalani N, Mohammadi A, Ghadimi LS, Ahadzadeh I, J. Colloid Interface Sci., 531, 369 (2018)
  55. Di J, Xia J, Yin S, Xu H, Xu L, Xu Y, He M, Li H, RSC Adv., 4, 14281 (2014)
  56. Gnayem H, Sasson Y, J. Phys. Chem. C, 119, 19201 (2015)
  57. Naushad M, Ahamad T, Al-Maswari BM, Alqadami AA, Alshehri SM, Chem. Eng. J., 330, 1351 (2017)
  58. Naushad M, Ahamad T, Sharma G, Al-Muhtaseb AH, Albadarin AB, Alam MM, ALOthman ZA, Alshehri SM, Ghfar AA, Chem. Eng. J., 300, 306 (2016)
  59. Xia J, Xu L, Zhang J, Yin S, Li H, Xu H, Di J, CrystEngComm, 15, 10132 (2013)
  60. Zhao DL, Yang X, Chen CL, Wang XK, J. Colloid Interface Sci., 398, 234 (2013)
  61. Piao SH, Bhaumik M, Maity A, Choi HJ, J. Mater. Chem. C, 3, 1861 (2015)
  62. Zhao D, Sheng G, Chen C, Wang X, Appl. Catal. B: Environ., 111-112, 303 (2012)
  63. Cheng H, Huang B, Qin X, Zhang X, Dai Y, Chem. Commun., 48, 97 (2012)
  64. Krishnakumar B, Swaminathan M, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 81, 739 (2011)
  65. Al-Othman ZA, Ali R, Naushad M, Chem. Eng. J., 184, 238 (2012)
  66. Vidya C, Manjunatha C, Chandraprabha M, Rajshekar M, MAL AR, J. Environ. Chem. Eng., 5, 3172 (2017)
  67. Chen LL, Feng SJ, Zhao DL, Chen SH, Li FF, Chen CL, J. Colloid Interface Sci., 490, 197 (2017)
  68. Abdelwahab NA, Helaly FM, J. Ind. Eng. Chem., 50, 162 (2017)
  69. Xu XQ, Liu RX, Cui YH, Liang XX, Lei C, Meng SY, Ma YL, Lei ZQ, Yang ZW, Appl. Catal. B: Environ., 210, 484 (2017)
  70. Liu HH, Chen DL, Wang ZQ, Jing HJ, Zhang R, Appl. Catal. B: Environ., 203, 300 (2017)