화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.79, 465-472, November, 2019
The textural and chemical changes in ACFs with E-beam and their influence on the detection of nerve agent simulant gases
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The textural (Brunauer-Emmett-Teller (BET)/density functional theory (DFT) surface energy) and chemical (oxygen-containing functional groups) properties of activated carbon fibers (ACFs) according to the electron-beam (E-beam) dose were investigated, and their dimethyl methylphosphonate (DMMP) gas sensing ability was tested. The E-beam attacked the basal plane in ACFs and generated additional lattice defects. The E-beam-irradiated ACFs exhibited a 22.2% change in resistance when upon exposure to DMMP gas. After E-beam irradiation, the surface energy of the ACFs increased because of increased roughness and oxygen-containing functional group content. As a result, the number of active sites capable of detecting DMMP increased, and the sensitivity increased.
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