화학공학소재연구정보센터
Inorganic Chemistry, Vol.58, No.12, 8237-8244, 2019
Transformation of the B-O Units from Corner-Sharing to Edge-Sharing Linkages in BaMBO4 (M = Ga, Al)
Two barium-containing borates BaMBO4 (M = Al, Ga) were synthesized via the solid-state method under atmospheric pressure. The 3D configurations of BaGaBO4 and BaAlBO4 are comprised of (2)(infinity)[Ba4O16](24-)/ (2)(infinity)[Ga4O10](8)(-)/[B2O5](4-) and (3)(infinity)[Ba4O16](24)(-)/(2)(infinity)[Al4O10](8-)/[B-4 O-10](8-), respectively, of which the [B4O10](8-) units possess unusual edge-sharing [BO4](5-) tetrahedra. From BaGaBO4 to BaAlBO4, the B-O units are transformed from corner-sharing to edge-sharing linkages, which arises from the directional shrinkage caused by the Ba-O and M-O skeletons. The phonon spectra of these two compounds do not show imaginary frequency at any wave vectors, indicating that both of them are kinetically stable.