화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.77, 262-272, September, 2019
Metal-organic framework MIL-53(Cr) as a superior adsorbent: Highly efficient separation of xylene isomers in liquid phase
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Selective adsorption and separation of three xylene isomers of seven stable metal-organic frameworks (MOFs) were investigated, where MIL-53(Cr) manifested the highest adsorption capacity and apparent preference for o-xylene. Further detailed studies with MIL-53(Cr) showed that pseudo-second order model fit best with adsorption kinetics of xylene isomers, and the isotherms were perfectly fitted by Langmuir isotherm model. The adsorption was proved to be a quick process, and both the changes of entropy and enthalpy contributed to the o-xylene selectivity, but which mainly resulted from the entropy effect. The adsorption capacity of preferable isomer o-xylene, on account of better packing efficiency, was record-breaking 8.19 mmol/g, and selectivity of OX/PX, OX/MX and MX/PX were 13.75, 8.01 and 1.72, respectively. Both the adsorption capacity and OX selectivity on MIL-53(Cr) in liquid phase adsorption and breakthrough experiments were super high, which discriminated it from zeolites and other materials reported so far. Combined with extremely short equilibrium time and high stability, MIL-53(Cr) can be a promising adsorbent for separation of xylenes in industrial process.
  1. Perry JJ, Bauer CA, Allendorf MD, Metal-Organic Frameworks Wiley-VCH Verlag & Co., KgaA, Weinheim, 2011.
  2. Sholl DS, Lively RP, Nature, 532(7600), 435 (2016)
  3. Lima RM, Grossmann IE, AIChE J., 55(2), 354 (2009)
  4. Lai Z, Bonilla G, Diaz I, Nery JG, Sujaoti K, Amat MA, Kokkoli E, Terasaki O, Thompson RW, Tsapatsis M, Vlachos DG, Science, 300, 456 (2003)
  5. Zheng HY, Yoshikawa M, J. Membr. Sci., 478, 148 (2015)
  6. Gu XH, Dong JH, Nenoff TM, Ozokwelu DE, J. Membr. Sci., 280(1-2), 624 (2006)
  7. Kurup AS, Hidajat K, Ray AK, Ind. Eng. Chem. Res., 44(15), 5703 (2005)
  8. Wu Z, Yang Y, Tu B, Webley PA, Zhao D, Adsorpt.-J. Int. Adsorpt. Soc., 15, 123 (2009)
  9. Mohammadi T, Rezaeian MP, Sep. Sci. Technol., 44(4), 817 (2009)
  10. Kiselev AV, Aratskova AA, Gvozdovitch TN, Yashin YI, J. Chromatogr. A, 195, 205 (1980)
  11. Murray LJ, Dinca M, Long JR, Chem. Soc. Rev., 38, 1294 (2009)
  12. Yoon M, Srirambalaji R, Kim K, Chem. Rev., 112(2), 1196 (2012)
  13. Lee J, Farha OK, Roberts J, Scheidt KA, Nguyen ST, Hupp JT, Chem. Soc. Rev., 38, 1450 (2009)
  14. Wu CD, Hu A, Zhang L, Lin WB, J. Am. Chem. Soc., 127(25), 8940 (2005)
  15. Kreno LE, Leong K, Farha OK, Allendorf M, Van Duyne RP, Hupp JT, Chem. Rev., 112(2), 1105 (2012)
  16. Furukawa H, Cordova KE, O’Keeffe M, Yaghi OM, Science, 341, 794 (2013)
  17. Wang HN, Meng X, Yang GS, Wang XL, Shao KZ, Su ZM, Wang CG, Chem. Commun., 47, 7128 (2011)
  18. Qin JS, Du DY, Li WL, Zhang JP, Li SL, Su ZM, Wang XL, Xu Q, Shao KZ, Lan YQ, Chem. Sci., 3, 2114 (2012)
  19. Ke F, Yuan YP, Qiu LG, Shen YH, Xie AJ, Zhu JF, Tian XY, Zhang LD, J. Mater. Chem., 21, 3843 (2011)
  20. Li JR, Kuppler RJ, Zhou HC, Chem. Soc. Rev., 38, 1477 (2009)
  21. Chen B, Liang C, Yang J, Contreras DS, Clancy YL, Lobkovsky EB, Yaghi OM, Dai S, Angew. Chem.-Int. Edit., 45, 1390 (2006)
  22. Zhang M, Pu ZJ, Chen XL, Gong XL, Zhu AX, Yuan LM, Chem. Commun., 49, 5201 (2013)
  23. Moreira MA, Santos JC, Ferreira AFP, Loureiro JM, Ragon F, Horcajada P, Yot PG, Serre C, Rodrigues AE, Langmuir, 28(7), 3494 (2012)
  24. Alaerts L, Kirschhock CE, Maes M, van der Veen MA, Finsy V, Depla A, Martens JA, Baron GV, Jacobs PA, Denayer JF, De Vos DE, Angew. Chem.-Int. Edit., 46, 4293 (2007)
  25. Finsy V, Verelst H, Alaerts L, De Vos D, Jacobs PA, Baron GV, Denayer JFM, J. Am. Chem. Soc., 130(22), 7110 (2008)
  26. Alaerts L, Maes M, Giebeler L, Jacobs PA, Martens JA, Denayer JFM, Kirschhock CEA, De Vos DE, J. Am. Chem. Soc., 130(43), 14170 (2008)
  27. Moreira MA, Santos JC, Ferreira AFP, Muller U, Trukhan N, Loureiro JM, Rodrigues AE, Sep. Sci. Technol., 46(13), 1995 (2011)
  28. El Osta R, Carlin-Sinclair A, Guillou N, Walton RI, Vermoortele F, Maes M, de Vos D, Millange F, Chem. Mat., 24, 2781 (2012)
  29. Peralta D, Barthelet K, Perezpellitero J, Chizallet C, Chaplais G, Simonmasseron A, Pirngruber GD, J. Phys. Chem. C, 116, 21844 (2012)
  30. Ahmed A, Forster M, Clowes R, Bradshaw D, Myers P, Zhang H, J. Phys. Chem. A, 1, 3276 (2013)
  31. Serre C, Millange F, Thouvenot C, Nogues M, Marsolier G, Louer D, Ferey G, J. Am. Chem. Soc., 124(45), 13519 (2002)
  32. Kang IJ, Khan NA, Haque E, Jhung SH, Chemistry, 17, 6437 (2011)
  33. Zhou X, Huang WY, Liu J, Wang HH, Li Z, Chem. Eng. Sci., 167, 98 (2017)
  34. Liu X, Li Y, Ban Y, Peng Y, Jin H, Bux H, Xu L, Caro J, Yang W, Chem. Commun., 49, 9140 (2013)
  35. Katz MJ, Brown ZJ, Colon YJ, Siu PW, Scheidt KA, Snurr RQ, Hupp JT, Farha OK, Chem. Commun., 49, 9449 (2013)
  36. Sindoro M, Jee AY, Granick S, Chem. Commun., 49, 9576 (2013)
  37. Huo SH, Yan XP, J. Mater. Chem., 22, 7449 (2012)
  38. Horcajada P, Surble S, Serre C, Hong DY, Seo YK, Chang JS, Greneche JM, Margiolaki I, Ferey G, Chem. Commun., 2820 (2007).
  39. Khutia A, Rammelberg HU, Schmidt T, Henninger S, Janiak C, Chem. Mat., 25, 790 (2013)
  40. Gu ZY, Yan XP, Angew. Chem.-Int. Edit., 49, 1477 (2010)
  41. Loiseau T, Serre C, Huguenard C, Fink G, Taulelle F, Henry M, Bataille T, Ferey G, Chem. Eng. J., 10, 1373 (2004)
  42. Yang YX, Bai P, Guo XH, Ind. Eng. Chem. Res., 56(50), 14725 (2017)
  43. Mingyang CLZZCQH, Chem. Ind. Eng. Prog., 31, 2167 (2012)
  44. Lim YI, Lee J, Bhatia SK, Lim YS, Han C, Ind. Eng. Chem. Res., 49(7), 3316 (2010)
  45. Azizian S, J. Colloid Interface Sci., 276(1), 47 (2004)
  46. Wu FC, Tseng RL, Juang RS, Chem. Eng. J., 153(1-3), 1 (2009)
  47. Foo KY, Hameed BH, Chem. Eng. J., 156(1), 2 (2010)
  48. Liu Y, J. Chem. Eng. Data, 54(7), 1981 (2009)
  49. Lima EC, Hosseini-Bandegharaei A, Moreno-Pirajan JC, Anastopoulos IJJOML, J. Mol. Liq., 273, 425 (2018)
  50. Torres-Knoop A, Dubbeldam D, ChemphysChem, 16, 2046 (2015)
  51. Dogan M, Abak H, Alkan M, J. Hazard. Mater., 164(1), 172 (2009)
  52. Maes M, Vermoortele F, Boulhout M, Boudewijns T, Kirschhock C, Ameloot R, Beurroies I, Denoyel R, De Vos DE, Microporous Mesoporous Mater., 157, 82 (2012)
  53. Agrawal M, Bhattacharyya S, Huang Y, Jayachandrababu KC, Murdock CR, Bentley JA, Rivas-Cardona A, Mertens MM, Walton KS, Sholl DS, Nair S, J. Phys. Chem. C, 122, 386 (2017)