화학공학소재연구정보센터
Journal of Materials Science, Vol.54, No.13, 9397-9413, 2019
Bi-modified 3D BiOBr microsphere with oxygen vacancies for efficient visible-light photocatalytic performance
Flower-like Bi that deposited BiOBr with oxygen vacancies (OVs) has been successfully fabricated via a simple solvothermal method followed by an easy hydrogenated treatment. The characterization results show that three-dimensional (3D) H-1.0Bi@BiOBr microspheres with the diameter about 1.2-1.5m were self-assembled by countless two-dimensional (2D) interlaced BiOBr nanosheets. Bi-deposited and oxygen vacancies endowed the H-1.0Bi@BiOBr samples with a dramatically enhanced photocatalytic performance for the degradation of organic pollutants (Rhodamine B and Ofloxacin) and the solar-energy nitrogen fixation. It disclosed that the photocatalytic performance order of the photocatalyst was H-200-1.0Bi@BiOBr>H-250-1.0Bi@BiOBr>H-150-1.0Bi@BiOBr>1.0Bi@BiOBr>2.0Bi@BiOBr>0.5Bi@BiOBr>BiOBr. Particularly, the enhanced photocatalytic activity was ascribed to higher BET specific area, enhanced visible-light absorption, effective photoinduced charge separation and suitable amounts of oxygen vacancies. The H-1.0Bi@BiOBr samples also showed good photochemical stability under repeated visible-light irradiation. This work could shed light on exploring high-photocatalytic-property materials and stimulating the development of OVs-Bi@BiOBr photocatalysts, which had great potential for the solar-energy conversion, environmental purification and organic pollution treatment in water.