The influence of metal precursor impregnation sequence has been analyzed in terms of catalytic activity and stability of Ni-Co/MgO catalysts for coke oven gas reforming of carbon dioxide. It is found that the metal precursor impregnation sequence overwhelmingly affected the interaction among Ni, Co and MgO and resulted in different CO2 sorption capacity. Compared to the catalysts prepared by first Ni precursor impregnation (Co/Ni/MgO) or by simultaneous Ni and Co precursor impregnation (NiCo/MgO), the catalysts prepared by first Co precursor impregnation (Ni/Co/MgO) obtained a stronger interaction among Ni, Co and MgO, leading to strong CO2 adsorption, smaller Ni particle size (9.6 nm), higher metal dispersion (10.6%), lower carbon deposition (1.5 wt%) and finally resulted in a superior catalytic activity and stability for coke oven gas reforming of carbon dioxide (CH4 and CO2 conversion were 55 +/- 1% and 80 +/- 2%, respectively). We also proposed a model for the effect of metal precursor impregnation sequence on the particle distribution of Ni and Co in Ni-Co/MgO catalyst. (C) 2019 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.