화학공학소재연구정보센터
International Journal of Hydrogen Energy, Vol.44, No.21, 11097-11110, 2019
Laminar burning characteristics of premixed methane-dissociated methanol-diluent mixtures
The influence of dissociated methanol (DM) and diluent (CO2 and N-2) addition on methane was investigated in a constant volume chamber under initial conditions of 3 bar and 343 K. CO was also added in separate proportions instead of DM under the same conditions to assess its effect. The laminar burning velocity, Markstein length and flame instability were analyzed systematically under various equivalence ratios (0.8-1.4), dissociated methanol gas ratios (40 and 80%), CO ratios (40 and 80%) and dilution ratios (0-15%). Furthermore, the flame speed of the fuel mixture and the production rate of key reactants were analyzed based on the calculation results of the Aramco Mech 2.0 mechanism to determine the influence principles of dilution. The results show that dissociated methanol gas increases the flame speed of the mixtures and promotes instability of the flame, and H-2 is the dominant component in enhancing the combustion process. Within the dilution ratio range of this study, the diluents decrease the laminar burning velocity of the mixtures since the addition of diluent gas decreases the concentration of key reactants, such as H and OH. The addition of diluent gas can inhibit the flame instability, but the effect is not clear. Compared with N-2, the effect of CO2 is more significant. (C) 2019 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.