화학공학소재연구정보센터
Fuel, Vol.247, 1-9, 2019
A superior liquid phase catalyst for enhanced absorption of NO2 together with SO2 after low temperature ozone oxidation for flue gas treatment
NOx and SO2 are the main air pollutants emitted from the coal-fired combustors. Since the typical combination of selective catalytic reduction (SCR) and we flue gas desulfurization (WFGD) is not suitable for some of industrial flue gas treatment due to their unsuitable temperature window and limited retrofitting space, new technologies must be developed. This paper proposes an effective we method for simultaneous removal of NOx and SO2. The insoluble NO was first oxidized into NO2 by ozone, and then NO2 together with SO2 were both absorbed in one we wash tower. To further improve NO2 removal efficiency, a new kind of additive was proposed and tested. Effects of various influence factors, such as additive concentration, residence time in the wash tower, liquid/gas ratios, initial NO/SO2/O-2 concentration and slurry pH value, were carefully evaluated in a home-designed experimental platform. Results indicated that the NOx removal efficiency was positively correlated with the increasing the additive concentration, while the maximum denitration and desulfurization efficiency were more than 95% and 86%. The NOx removal efficiency was enhanced with the increasing residence time and liquid/gas ratios. The alkaline environment was verified to be beneficial for the simultaneous absorption process. The exiting O-2 in flue gas would not consume additives, and the denitration and desulfurization efficiency were insensitive to the initial NO and SO 2 concentration as well. Only 2% decrease of the denitration efficiency was observed after 300 mins stability test, while the desulfurization efficiency kept > 98%. With the characterizations of Ion Chromatograph (IC), NO2-, NO3- and SO42- were detected as the main absorption by-products anions, whereas NO2- accumulation would inhibit the overall NOx removal. Finally, the mechanism of simultaneous removal of SO2 and NO using the novel liquid phase catalyst was proposed and discussed.