화학공학소재연구정보센터
Electrochimica Acta, Vol.304, 70-79, 2019
Ba0.95Ca0.05Ce0.9Y0.1O3 as an electrolyte for proton-conducting ceramic fuel cells
Comparative studies of the physicochemical and electrochemical properties of BaCe0.9Y0.1O3 and Ba0.95Ca0.05Ce0.9Y0.1O3 sintered ceramics are described. The orthorhombic (Pnma) space group was determined for both investigated samples within the temperature range 25-800 degrees C, using the X-ray diffraction method. A decrease in the cell volume of Ba0.95Ca0.05Ce0.9Y0.1O3 compared to that of BaCe0.9Y0.1O3 was observed within the investigated temperature range. It was found that the partial substitution of calcium for barium, resulting in Ba0.95Ca0.05Ce0.9Y0.1O3, caused an increase in specific free volume and global instability index compared to the original composition BaCe0.9Y0.1O3. Improvement of the chemical resistance of Ba0.95Ca0.05Ce0.9Y0.1O3 in a CO2 gas atmosphere was observed. It was found that Ba0.95Ca0.05Ce0.9Y0.1O3 exhibited a slightly lower level of electrical conductivity than BaCe0.9Y0.1O3 in air as well as in Ar-H-2 gas atmospheres. The greater chemical resistance of Ba0.95Ca0.05Ce0.9Y0.1O3 in a CO2 gas atmosphere enhances the suitability of the modified material as an electrolyte for fuel cells with proton-conducting ceramics. The electrochemical response of the interface (La0.60Sr0.40)(0.95)Co0.20Fe0.80O3-delta vertical bar Ba0.95Ca0.05Ce0.9Y0.1O3 was also investigated within the applied potential range from -0.05 to -0.5 V in SOFC mode as well as from 0.05 to 0.5 V in SOEC mode); it was found that the current reached a fairly stable value over time. (C) 2019 Elsevier Ltd. All rights reserved.