화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.74, 158-163, June, 2019
Functionalized mesoporous metal-organic framework PCN-100: An efficient carrier for vitamin E storage and delivery
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A mesoporous metal-organic-framework with amino group, PCN-100, was modified with terephthaloyl chloride (TC). The adsorption/delivery of vitamin E were carried out with pristine PCN-100, TC-modified PCN-100 (TC-PCN-100) and activated carbon (AC). The adsorbed quantity was in the order: AC < TC-PCN- 100 < PCN-100; however, the delivery rate was in the order: TC-PCN-100 < PCN-100 < AC. Importantly, the release rate of vitamin E from TC-PCN-100 was considerably lower than that from PCN-100 and AC; and this slow release could be explained with hydrophobic, π-π and H-bonding interactions. Moreover, the delivery rate from PCN-100s could be decreased by decreasing pH.
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