화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.36, No.5, 753-762, May, 2019
DOI10.1007/s11814-019-0261-7  Export Citation
Preparation of mesoporous silica from coal slag and its metal ion adsorption behavior
Xinying Zhang1, Yu Wu1, 2, Xuefang Li1, 2, Xianlong Meng1, 2, Huihu Shi1, 2, Zhaojun Wu1, 2, and Jianbin Zhang1, 2, †
  • 1College of Chemical Engineering, Inner Mongolia University of Technology, Hohhot 010051, China
  • 2Inner Mongolia Engineering Research Center for CO2 Capture and Utilization, Hohhot 010051, China
E-mail:
A novel mesoporous silica (MS) with the high specific surface area up to 1,199m2/g was prepared from coal slag by SO3 2 - leaching and hydrothermal synthesis. Its application in metal ion removal was explored using Pb2+, Cu2+, Co2+ and Cd2+ as the model ions. The effects of adsorption time, pH, initial metal ion concentration, adsorbent dosage and adsorption temperature on the metal ion adsorption behaviors of the as-prepared MS were systematically, and the maximum adsorption capacities were measured to be 55.76mg·g-1, 33.49mg·g-1, 24.29mg·g-1 and 22.98mg· g-1 for Pb2+, Cu2+, Co2+ and Cd2+, respectively. The metal ion adsorption on the as-prepared MS followed pseudo-second- order kinetics, and the adsorption isotherm fitted the Langmuir isotherm model, indicating that the adsorption was spontaneous, endothermic and enthalpy driven.
Keywords:Mesoporous Silica;Coal Slag;Hydrothermal Synthesis;Metal Ion;Adsorption Behaviors
  1. Li C, Wan JH, Sun HH, Li LT, J. Hazard. Mater., 179(1-3), 515 (2010)
  2. Kondratiev A, Ilyushechkin A, Fuel, 224, 783 (2018)
  3. Tanaka H, Sakai Y, Hino R, Mater. Res. Bull., 37(11), 1873 (2002)
  4. Nisnevich M, Sirotin G, Schlesinger T, Eshel Y, Fuel, 87(8-9), 1610 (2008)
  5. Park M, Choi CL, Lim WT, Kim MC, Choi J, Heo NH, Microporous Mesoporous Mater., 37, 81 (2000)
  6. Zevenbergen C, Bradley JP, Reeuwijk LPV, Shyam AK, Hjelmar O, Comans RNJ, Environ. Sci. Technol., 33(19), 3405 (1999)
  7. Li Y, Liu Y, Gong XZ, Nie ZR, Cui S[, Wang ZH, Chen WJ, J. Clean Prod., 120(175), 221 (2016)
  8. Pan DA, Li LL, Wu YF, Liu TT, Yu HL, J. Clean Prod., 175, 251 (2018)
  9. Torkittikul P, Nochaiya T, Wongkeo W, Chaipanich A, J. Mater. Cycles. Waste, 19(1), 305 (2017)
  10. Rivera N, Hesterberg D, Kaur N, Duckworth OW, Energy Fuels, 31(9), 9652 (2017)
  11. Hui K, Chao C, Microporous Mesoporous Mater., 88, 145 (2006)
  12. Yan F, Jiang JG, Tian SC, Liu ZW, Shi J, Li KM, Chen XJ, Xiu YW, ACS Sustain. Chem. Eng., 4(9), 4654 (2016)
  13. Serrano DP, Grieken RV, Melgares AM, Moreno J, J. Am. Ceram. Soc., 17(4), 387 (2010)
  14. Liu HT, Bao XJ, Wei WS, Shi G, Microporous Mesoporous Mater., 66, 117 (2003)
  15. Zhang RY, Ding W, Tu B, Zhao DY, Chem. Mater., 19, 4379 (2007)
  16. Kruk M, Jaroniec M, Sayari A, J. Phys. Chem. B, 101(4), 583 (1997)
  17. Van der Voort P, Mathieu M, Mees F, Vansant EF, J. Phys. Chem. B, 102(44), 8847 (1998)
  18. Lee HJ, Park KK, Kupnik M, Melosh NA, Khuriyakub BT, Anal. Chem., 84(7), 3063 (2012)
  19. Zhang DH, Xiao DY, Yu Q, Chen SF, Miao MH, ACS Sustain. Chem. Eng., 5(11), 10258 (2017)
  20. Nakamizu A, Kasai T, Nakazawa J, Hikichi S, ACS Omega, 2(3), 1025 (2017)
  21. Huang SJ, Hung CT, Zheng AM, Lin JS, Yang CF, Chang YC, Deng F, Liu SB, J. Phys. Chem. Lett., 5, 3183 (2014)
  22. Climent MJ, Corma A, Iborra S, Navarro MC, Primo J, J. Catal., 161(2), 783 (1996)
  23. Clifford D, Subramonian S, Sorg TJ, Environ. Sci. Technol., 20(11), 1072 (1986)
  24. Babel S, Kurniawan TA, J. Hazard. Mater., 97(1-3), 219 (2003)
  25. Hui KS, Chao CYH, Kot SC, J. Hazard. Mater., 127(1-3), 89 (2005)
  26. Sayari A, Hamoudi S, Yang Y, Chem. Mater., 17(1), 212 (2005)
  27. Ruparelia JP, Duttagupta SP, Chatterjee AK, Mukherji S, Desalination, 232(1-3), 145 (2008)
  28. Lin SH, Juang RS, J. Hazard. Mater., 92(3), 315 (2002)
  29. Ho YS, Ofomaja AE, J. Hazard. Mater., 129(1-3), 137 (2006)
  30. Martinson L, Alveteg M, Warfvinge P, Environ. Pollut., 124(1), 119 (2003)
  31. Gao Q, Li H, Ling Y, Han B, Xia K, Zhou C, Microporous Mesoporous Mater., 241, 409 (2017)
  32. Prasad M, Saxena S, Amritphale SS, Chandra N, Ind. Eng. Chem. Res., 39(8), 3034 (2000)
  33. Ding DH, Lei ZF, Yang YN, Feng CP, Zhang ZY, ACS Appl. Mater. Interfaces, 5(20), 10151 (2013)
  34. Kageyama K, Tamazawa J, Aida T, Science, 285, 2113 (1999)
  35. Takahashi H, Li B, Sasaki T, Miyazaki C, Kajino T, Inagaki S, Chem. Mater., 12, 3301 (2000)
  36. Yuan G, Zhang J, Zhang Y, Yan Y, Ju X, Sun J, Korean J. Chem. Eng., 32(3), 436 (2015)
  37. Romero AA, Alba MD, Zhou WZ, Klinowski J, J. Phys. Chem. B, 101(27), 5294 (1997)
  38. Takahashi R, Sato S, Sodesawa T, Kawakita M, Ogura K, J. Phys. Chem. B, 104(51), 12184 (2000)
  39. Jesionowski T, Powder Technol., 127(1), 56 (2002)
  40. Venkateswarlu S, Kumar BN, Prathima B, SubbaRao Y, Jyothi NVV, Arabian J. Chem., 7, 1878 (2014)
  41. Putra WP, Kamari A, Yusoff SNM, Ishak CF, Mohamed A, Hashim N, Isa IM, J. Encapsulation Adsorpt. Sci., 4, 25 (2014)
  42. Paulino AG, Cunha AJD, Alfaya RVDS, Alfaya AADS, Water Treat., 52, 4223 (2014)
  43. Kamel K, Zboon A, Bashar M, Smadi A, Khawaldh A, Water Air Soil Pollut., 227, 248 (2016)
  44. Kamel A, Mohammad A, Hani FB, J. Hazard. Mater., 188, 414 (2011)
  45. Mohammad S, Harahsheh A, Kamel AZ, Leema AM, Chem. Eng. J., 3, 1669 (2015)
  46. Dong Z, Wang D, Liu X, Pei XF, Chen LW, Jin J, J. Mater. Chem. A, 2, 5034 (2014)
  47. Zhu Y, Hu J, Wang J, Prog. Nucl. Energy, 71, 172 (2014)
  48. Lin LC, Thirumavalavan M, Wang YT, Lee JF, Colloids Surf. A: Physicochem. Eng. Asp., 369, 223 (2010)
  49. Moroi GN, Avram E, Bulgariu L, Water Air Soil Pollut., 227, 260 (2016)
  50. Bessbousse H, Rhlalou T, Verchere JF, Lebrun L, J. Membr. Sci., 307(2), 249 (2008)