화학공학소재연구정보센터
Polymer(Korea), Vol.43, No.2, 169-180, March, 2019
수분산 폴리우레탄 코팅의 미세상분리와 물성에 Isosorbide가 미치는 영향
Effects of Isosorbide on the Microphase Separation and Properties of Waterborne Polyurethane Coatings
E-mail:
Series of waterborne polyurethanes (WPUs) containing poly(tetra methylene glycol) (PTMG), 4,4-dicyclohexylmethane diisocyanate (HMDI), 2,2-dimethylolpropionic acid (DMPA), 2,2,4-trimethyl-1,3-pentanediol (TMPD), isosorbide (ISO) and ethylenediamine (EDA) were synthesized. The effects of ISO on the structure and properties of WPUs were studied by gel permeation chromatography (GPC), Fourier-transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), dynamic mechanical analyzer (DMTA), X-ray diffraction (XRD), thermogravimetry (TG), mechanical test, chemical resistance and hardness test. The deconvolution analysis of FTIR of WPUs revealed that the hydrogen bond interaction in the WPUs increased with the increase of ISO content. Furthermore, the degree of microphase separation was increased with the increase of hydrogen bond interaction, which was confirmed by DSC, XRD and DMTA test. The results demonstrated that the addition of ISO can increase the hydrogen bond interaction between the hard and hard segments in WPUs, which improved the mechanical properties of the WPU films. The highest tensile strength was obtained of 59.67 MPa when the content of isosorbide was 10.35 wt%. Moreover, the ISO was helpful to improve the chemical resistance and hardness of the coatings by the comprehensive performance analysis.
  1. Zia KM, Noreen A, Zuber M, Tabasum S, Mujahid M, Int. J. Biol. Macromol., 82, 1028 (2016)
  2. Jung JY, Lee JM, Hong SK, Lee JK, Jung HM, Kim YS, Polym. Korea, 39(2), 235 (2015)
  3. Jiang T, Wang W, Yu D, Huanf D, Wei N, Hu Y, Huang H, J. Polym. Res., 25, 140 (2018)
  4. Oprea S, Potolinca VO, Oprea V, Eur. Polym. J., 83, 161 (2016)
  5. Blache H, Mechin F, Rousseau A, Fleury E, Pascault JP, Alcouffe P, Jacquel N, Loup RS, Ind. Crop. Prod., 121, 303 (2018)
  6. Lee S, Kim S, Hong IK, Polym. Korea, 39(2), 287 (2015)
  7. Marin R, Alla A, de Ilarduya AM, Munoz-Guerra S, J. Appl. Polym. Sci., 123(2), 986 (2012)
  8. Calvo-Correas T, Martin MD, Retegi A, Gabilondo N, Corcuera MA, Eceiza A, ACS Sustainable Chem. Eng., 4, 5684 (2016)
  9. Javni I, Bilic O, Bilic N, Petrovic ZS, Eastwood EA, Zhang F, Ilavsky J, J. Appl. Polym. Sci., 132, 42830 (2015)
  10. Javni I, Bilic O, Bilic N, Petrovic ZS, Eastwood EA, Zhang F, Ilavsky J, Polym. Int., 64, 1607 (2015)
  11. Han JH, Hong YT, Kim HJ, Polym. Korea, 42(4), 670 (2018)
  12. Han X, Tao C, Xie Z, Bao J, Huang Y, Xu G, Polym. Korea, 41(3), 378 (2017)
  13. Ko YS, Yim JH, Polym. Korea, 37(5), 587 (2013)
  14. Yin X, Dong C, Chai C, Luo Y, Prog. Org. Coat., 122, 119 (2018)
  15. Lee CR, Jeong EY, Jo NJ, Polym. Korea, 42(2), 320 (2018)
  16. Xia Y, Larock RC, ChemSusChem, 4, 386 (2011)
  17. Li Y, Noordover BAJ, van Benthem RATM, Koning CE, Eur. Polym. J., 59, 8 (2014)
  18. Li Y, Noordover BAJ, van Benthem RATM, Koning CE, Eur. Polym. J., 52, 12 (2014)
  19. Zhang CX, Ren ZY, Yin ZG, Qian HY, Ma DZ, Polym. Bull., 60(1), 97 (2008)
  20. Lee HS, Wang YK, MacKnight WJ, Hsu SL, Macromolecules, 21, 270 (1988)
  21. Kwak YS, Kim EY, Yoo BH, Kim HD, J. Appl. Polym. Sci., 94(4), 1743 (2004)
  22. Princi E, Vicini S, Castro K, Capitani D, Proietti N, Mannina L, Macromol. Chem. Phys., 210(4), 879 (2009)
  23. Spirkova M, Pavlicevic J, Strachota A, Poreba R, Bera O, Kapralkova L, Baldrian J, Slouf M, Lazic N, Budinski-Simendic J, Eur. Polym. J., 47, 959 (2011)
  24. Hong L, Shi LY, Tang XZ, Macromolecules, 36(13), 4989 (2003)
  25. Ma Y, Liu J, Luo M, Xing J, Wu J, Pan H, Ruan C, Luo Y, RSC Adv.,, 7, 13886 (2017)
  26. Pan H, Chen D, Eur. Polym. J., 43, 3766 (2007)
  27. Wang L, Shen Y, Lai X, Li Z, Liu M, J. Polym. Res., 18, 469 (2011)
  28. Kontou E, Spathis G, Niaounakis M, Kefalas V, Colloid Polym. Sci., 268, 636 (1990)
  29. Łukaszczyk J, Janicki B, Kaczmarek M, Eur. Polym. J., 47, 1601 (2011)
  30. Fang C, Zhou X, Yu Q, Liu S, Guo D, Yu R, Hu J, Prog. Org. Coat., 77, 61 (2014)
  31. Fang C, Zhou X, Yu Q, Liu S, Guo D, Yu R, Hu J, Prog. Org. Coat., 77, 61 (2014)
  32. Bao LH, Lan YJ, Zhang SF, Iran. Polym. J., 15, 737 (2006)
  33. Lin WT, Lee WJ, Colloids Surf. A: Physicochem. Eng. Asp., 522, 453 (2017)
  34. Santos CC, Delpech MC, Coutinho FMB, J. Mater. Sci., 44(5), 1317 (2009)
  35. Du Y, Zhang JS, Zhou C, Polym. Bull., 73(1), 293 (2016)
  36. Shendi HK, Omrani I, Ahmadi A, Farhadian A, Babanejad N, Nabid MR, Prog. Org. Coat., 105, 303 (2017)
  37. Corcuera MA, Rueda L, d’Arlas BF, Arbelaiz A, Marieta C, Mondragon I, Eceiza A, Polym. Degrad. Stabil., 95, 2175 (2010)
  38. Akbarian M, Olya ME, Ataeefard M, Mahdavian M, Prog. Org. Coat., 75, 344 (2012)
  39. Howard GT, Int. Biodeterior. Biodegrad., 49, 245 (2002)