Fluid Phase Equilibria, Vol.479, 17-24, 2019
Solid-liquid equilibria for selected binary systems containing diphenyl carbonate
The solid-liquid.equilibrium (SLE) data for five binary systems containing diphenyl carbonate (DPC), i.e., ethanol, 1-propanol, 2-propanol, diethyl carbonate, or dipropyl carbonate + DPC, were determined experimentally. We designed a new experimental apparatus based on a synthetic method for the SLE measurements. We verified the applicability of the designed apparatus by determining the binary SLE data for the system dimethyl carbonate + DPC. The experimental SLE data were represented by a non-random two-liquid model. Predictions of SLE data for the binary systems were also tested on the basis of the National Institution of Standards and Technology-modified universal functional activity coefficient group contribution model. (C) 2018 Elsevier B.V. All rights reserved.