화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.72, 380-389, April, 2019
Graphene oxide crosslinked poly(phenylene oxide) nanocomposite as high-performance anion-conducting membrane
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Anion conducting nanocomposite membranes were synthesized by crosslinking quaternized poly (phenylene oxide) with 1,4-diazabicyclo[2.2.2]octane modified graphene oxide (QGO). FTIR, SEM, AFM and TEM were used to study the functionalization, structure, and morphology of the membranes. The effect of QGO on ionic conductivity, water uptake, and swelling ratio were studied in detail. The nanocomposite membrane exhibited an ionic conductivity of ~90 mS cm-1 at 25 °C and reached 151 mS cm-1 at 80 °C owing to good microphase separation. A power density of 5.2 mW cm -2 at 60 °C for urea/O2 fuel cell was obtained using the nanocomposite membrane.
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