화학공학소재연구정보센터
Journal of the American Chemical Society, Vol.140, No.32, 10075-10079, 2018
Hydrogen Bonds Dictate O-2 Capture and Release within a Zinc Tripod
Six directed hydrogen bonding (H-bonding) interactions allow for the reversible capture and reduction of dioxygen to a trans-1,2-peroxo within a tripodal zinc(II) framework. Spectroscopic studies of the dizinc peroxides, as well as on model zinc diazides, suggest H-bonding contributions serve a dominant role for the binding/activation of these small molecules.