화학공학소재연구정보센터
Journal of the American Chemical Society, Vol.140, No.40, 12765-12769, 2018
Site-Selective Ni-Catalyzed Reductive Coupling of alpha-Haloboranes with Unactivated Olefins
A mild, chemo- and site-selective catalytic protocol that allows for incorporating an alkylboron fragment into unactivated olefins is described. The use of internal olefins enables C-C bond-formation at remote sp(3) C-H sites, constituting a complementary and conceptually different approach to existing borylation techniques that are currently available at sp(3) centers.