화학공학소재연구정보센터
Journal of Colloid and Interface Science, Vol.531, 282-290, 2018
Impacts of morphology on fouling propensity in a membrane bioreactor based on thermodynamic analyses
Impacts of morphologies of both membrane and foulant on interaction energies related with adhesive fouling in a membrane bioreactor (MBR) were explored by thermodynamic analyses. Interaction energies in three possible interaction scenarios regarding different membrane and foulant morphologies under conditions in this study were quantified according to the thermodynamic methods. It was interestingly found that, strength of total interaction between soluble microbial products (SMPs) and rough membrane was over 20,000 times of that between sludge flocs and rough membrane under same conditions, indicating the extremely higher adhesion ability of SMPs than the large particulate foulants. This result plausibly explained the high fouling propensity of SMPs over sludge flocs. As compared with smooth surfaces, rough surfaces of both membrane and sludge flocs significantly reduced total interaction strength, alleviating adhesive fouling caused by the sludge flocs. Reduce in fractal dimension (D-f) of membrane increased adhesive fouling caused by the SMPs, but alleviated adhesive fouling caused by the sludge flocs. These findings gave important implications to better understand and control membrane fouling in MBRs. (C) 2018 Elsevier Inc. All rights reserved.