화학공학소재연구정보센터
Korean Journal of Chemical Engineering, Vol.35, No.11, 2145-2149, November, 2018
Continuous methanol synthesis directly from methane and steam over Cu(II)-exchanged mordenite
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The formation of methanol directly from methane and steam was observed over Cu ion-exchanged mordenite. Furthermore, the continuous production of methanol was achieved by co-feeding methane and steam over Cumordenite. The methanol production rate was comparable to that reported in the stepwise process in which activation, methane reaction, and extraction of methanol were carried out separately.
  1. Kerr RA, Science, 328(5986), 1624 (2010)
  2. Aasberg-Petersen K, Dybkjær I, Ovesen CV, Schjødt NC, Sehested J, Thomsen SG, J. Nat. Gas Sci. Eng., 3, 423 (2011)
  3. Hammond C, Conrad S, Hermans I, ChemSusChem, 5, 1668 (2012)
  4. Schwach P, Pan XL, Bao XH, Chem. Rev., 117(13), 8497 (2017)
  5. Tian P, Wei Y, Ye M, Liu Z, ACS Catal., 5, 1922 (2015)
  6. Gunsalus NJ, Koppaka A, Park SH, Bischof SM, Hashiguchi BG, Periana RA, Chem. Rev., 117(13), 8521 (2107)
  7. Ravi M, Ranocchiari M, van Bokhoven JA, Angew. Chem.-Int. Edit., 56, 16464 (2017)
  8. Sushkevich VL, Palagin D, Ranocchiari M, van Bokhoven JA, Science, 356(6337), 523 (2017)
  9. Sushkevich VL, Palagin D, van Bokhoven JA, Angew. Chem.-Int. Edit., 57, 8906 (2018)
  10. Kim Y, Kim TY, Lee H, Yi J, Chem. Commun., 53(29), 4116 (2017)
  11. Bozbag SE, Alayon EMC, Pechacek J, Nachtegaal M, Ranocchiari M, van Bokhoven JA, Catal. Sci. Technol., 6(13), 5011 (2016)
  12. Park MB, Ahn SH, Mansouri A, Ranocchiari M, van Bokhoven JA, ChemCatChem, 9(19), 3705 (2017)
  13. Narsimhan K, Iyoki K, Dinh K, Roman-Leshkov Y, ACS Cent. Sci., 2(6), 424 (2016)