화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.65, 224-235, September, 2018
Preparation, self-assembly and performance modulation of gold nanoparticles decorated ferrocene-containing hybrid block copolymer multifunctional materials
E-mail:,
Gold nanoparticles decorated stimuli-responsive copolymer hybrids, poly(2-methacryloyloxyethyl ferrocenecarboxylate)-block-poly(N-isopropylacryamide) decorated with gold nanoparticles, were synthesized through two-step successive RAFT and ensuing in-situ reduction. The hybrids could selfassemble into interesting micelle structures from globular, wormlike to rodlike shapes by altering the quality and compositions of solvents and ionic strength, and exhibited multifunctionality including quasi-reversible electrochemical behavior, redox-stress responsiveness and temperature sensitivity. The physicochemical and electrochemical properties were modulated by tailor-making the system compositions and redox reaction. The copolymer hybrids were expected to broaden their applications in nanobiomedicine including targeted drug carriers and magnetic resonance imaging, optical, electrochemical catalyst, optoelectronics and sensors etc.
  1. Christodoulou L, Venables JD, JOM, 55, 39 (2003)
  2. Kim HC, Sastry AM, J. Intel. Mater. Syst. Struct., 23, 1787 (2012)
  3. Cha C, Shin SR, Annabi N, Dokmeci MR, Khademhosseini A, ACS Nano, 7, 2891 (2013)
  4. Badami V, Ahuja B, Sci. World J., 2014, 986912 (2014)
  5. Huang X, El-Sayed MA, J. Adv. Res., 1, 13 (2010)
  6. Stewart ME, Anderton CR, Thompson LB, Maria J, Gray SK, Rogers JA, Nuzzo RG, Chem. Rev., 108(2), 494 (2008)
  7. Dehn MH, Arseneau DJ, Boni P, Bridges MD, Buck T, J. Chem. Phys., 145, 293 (2016)
  8. Cobley CM, Chen J, Cho EC, Wang LV, Xia Y, Chem. Soc. Rev., 40, 44 (2011)
  9. Cobley CM, Chen J, Cho EC, Wang LV, Xia Y, Cheminform, 42, 44 (2011)
  10. Cormode DP, Roessl E, Thran A, Skajaa T, Gordon RE, Schlomka JP, Fuster V, Fisher EA, Mulder WJ, Proksa R, Fayad ZA, Radiology, 256, 774 (2010)
  11. Cao C, Gontard LC, Tram LLT, Wolff A, Bang DD, Small, 7, 1701 (2011)
  12. Hu WH, Chen HM, Zhang HH, He GL, Li X, Zhang XX, Liu Y, Li CM, J. Colloid Interface Sci., 431, 71 (2014)
  13. Jaramillo TF, Baeck SH, Cuenya BR, McFarland EW, J. Am. Chem. Soc., 125(24), 7148 (2003)
  14. Qi ZM, Honma I, Ichihara M, Zhou HS, Adv. Funct. Mater., 16(3), 377 (2006)
  15. Brown SD, Nativo P, Smith JA, Stirling D, Edwards PR, Venugopal B, Flint DJ, Plumb JA, Graham D, Wheate NJ, J. Am. Chem. Soc., 132(13), 4678 (2010)
  16. Wang D, Jin Y, Zhu X, Yan D, Prog. Polym. Sci, 64, 114 (2017)
  17. Cabane E, Zhang X, Langowska K, Palivan CG, Meier W, Biointerphases, 7, 9 (2012)
  18. Gao C, Liu C, Zhou H, Wang S, Zhang W, Polym. Chem, 54, 900 (2016)
  19. Funasako Y, Inagaki T, Mochida T, Sakurai T, Ohta H, Furukawa K, Nakamurad T, Dalton Trans., 42, 8317 (2013)
  20. Mahmoud WH, Mahmoud NF, Mohamed GG, J. Therm. Anal. Calorim., 3, 1 (2017)
  21. Saleem M, Wang L, Yu H, Abdin Z, Akram M, Ullah RS, Colloid Polym. Sci., 295, 995 (2017)
  22. Yuan W, Zhao Z, Yuan J, Gu S, Zhang F, Xie XM, Ren J, Polym. Int., 60, 194 (2011)
  23. Li J, He WD, Sun XL, J. Polym. Sci. A: Polym. Chem., 45(22), 5156 (2007)
  24. Otsuka I, Travelet C, Halila S, Fort S, Pignot-Paintrand I, Narumi A, Borsali R, Biomacromolecules, 13(5), 1458 (2012)
  25. Corbierre MK, Cameron NS, Sutton M, Mochrie SGJ, Lurio LB, Ruhm A, Lennox RB, J. Am. Chem. Soc., 123(42), 10411 (2001)
  26. Choudhary M, Brink R, Nandi D, Siwal S, Mallick K, J. Mater. Sci., 52(2), 770 (2017)
  27. Otsuka I, Osaka M, Sakai Y, Travelet C, Putaux JL, Borsali R, Langmuir, 29(49), 15224 (2013)
  28. Bouilhac C, Travelet C, Graillot A, Monge S, Borsali R, Robin JJ, Polym. Chem., 5, 2756 (2014)
  29. Liu Y, Yang A, Liu B, Yin D, Speciality Petrochem., 32, 32 (2015)
  30. Xu Y, Wang L, Li Y, Wang C, Carbohydr. Polym., 114, 27 (2017)
  31. Feng C, Gu L, Yang D, Hu JH, Lu GL, Huang XY, Polymer, 50(16), 3990 (2009)
  32. Pang XH, Li JX, Zhao YB, Wu D, Zhang Y, Du B, Ma HM, Wei Q, ACS Appl. Mater. Interfaces, 7, 19260 (2015)
  33. Adhikari B, Afrasiabi R, Kraatz H, Organometallics, 32, 5899 (2013)
  34. Li G, Zeng CG, Jin RC, J. Phys. Chem. C, 119, 11143 (2015)
  35. Gadogbe M, Zhou Y, Alahakoon SH, Perera GS, Zou SL, Pittman CU, Zhang DM, J. Phys. Chem. C, 119, 18414 (2015)
  36. Kabanov AV, Nazarova IR, Astafieva IV, Batrakova EV, Alakhov VY, Yaroslavov AA, Kabanov VA, Macromolecules, 28(7), 2303 (1995)
  37. Yue CY, Chen WD, Jiang FL, Feng R, Hong MC, Inorg. Chem. Commun., 13, 105 (2013)
  38. Luo YL, Huang RJ, Zhang LL, Xu F, Chen YS, Colloids Surf. A: Physicochem. Eng. Asp., 436, 1175 (2013)
  39. Li Y, Zaluzhna O, Xu BL, Gao YA, Modest JM, Tong YJ, J. Am. Chem. Soc., 133(7), 2092 (2011)
  40. Shipway AN, Katz E, Willner I, ChemphysChem, 1, 18 (2000)
  41. Daniel MC, Astruc D, Chem. Rev., 104(1), 293 (2004)
  42. Cao Y, Li H, Zuo J, Niu A, Acta Polym. Sin., 3, 345 (2000)
  43. Wang YP, Hao H, Wei XX, Fan A, Zhang FY, Ion Exch. Adsorpt., 29, 569 (2013)
  44. Kuperkar K, Abezgauz L, Danino D, Verma G, Hassan PA, Aswal VK, Varade D, Bahadur P, J. Colloid Interface Sci., 323(2), 403 (2008)
  45. Israelachvili JN, Intermolecular and Surface Forces, third ed., Academic Press, 2010.
  46. Trickett K, Eastoe J, Adv. Colloid Interface Sci., 144, 66 (2008)
  47. Yu Y, Kieviet BD, Liu F, Siretanu I, Kutnyanszky E, Vancso GJ, Beer SD, Soft Matter, 11, 8508 (2015)
  48. Sahn M, Yildirim T, Dirauf M, Weber C, Sungur P, Hoeppener S, Schubert US, Macromolecules, 49(19), 7257 (2016)
  49. Tan QH, Wang L, Ma L, Yu HJ, Ding JH, Liu QQ, Xiao AG, Ren GQ, J. Phys. Chem. B, 112(35), 11171 (2008)
  50. Enrıquez A, Gonzalez-Vadillo AM, Martınez-Montero S, Bruna L, Cuadrado I, Organometallics, 33, 7307 (2014)
  51. Chang YY, Xie SB, Chai YQ, Yuan YL, Yuan R, Chem. Commun., 51, 7657 (2015)
  52. Liu LC, Rui LL, Gao Y, Zhang WA, Polym. Chem., 6, 1817 (2015)
  53. Kihara N, Hashimoto M, Takata T, Org. Lett., 6, 1693 (2004)