화학공학소재연구정보센터
Fuel Processing Technology, Vol.176, 119-123, 2018
Tandem mass spectrometric evaluation of core structures of aromatic compounds after catalytic deoxygenation
Catalytic deoxygenation of coal enhances the stability and combustion performance of coal-derived liquid fuels. However, determination of the selectivity of removal of oxygen atoms incorporated in or residing outside of aromatic rings is challenging. This limits the ability to evaluate the success of catalytic deoxygenation processes. A mass spectrometric method, in-source collision-activated dissociation (ISCAD), combined with high resolution product ion detection, is demonstrated to allow the determination of whether the oxygen atoms are in aromatic compounds reside outside of aromatic rings or part of the aromatic system, because alkyl chains can be removed from aromatic cores via ISCAD. Application of this method for the analysis of a subbituminous coal treated using a supported catalyst revealed that the catalytic treatment reduced the number of oxygen-containing hetero-aromatic rings but not the number of oxygen atoms residing outside the aromatic rings.