화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.63, 449-455, July, 2018
Toluene abatement through adsorption and plasma oxidation using ZSM-5 mixed with γ-Al2O3, TiO2 or BaTiO3
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Toluene abatement through adsorption and then plasma oxidation using ZSM-5, ZSM-5-γ-Al2O3(Z-Al), ZSM-5-TiO2 (Z-Ti), ZSM-5-BaTiO3 (Z-Ba), and AgMn/ZSM-5-BaTiO3 (AgMn/Z-Ba) as adsorbents/catalysts was investigated. The efficiency of toluene removal reached ~100% for all the tested adsorbents/catalysts. ZSM-5 had the lowest mineralization rate (MR) of ~43%, while Z-Ba had the highest MR (88%) with an SCO2 of ~80%. After loading AgMn onto Z-Ba, both the breakthrough capacity of toluene and SCO2 was increased, while the production of byproduct O3 and MR was decreased. The mixed materials created a higher amount of active species capable of deeply oxidizing adsorbed toluene.
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