화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.63, 322-339, July, 2018
In-situ synthesis of Zn doped polyaniline on graphene oxide for inhibition of mild steel corrosion in 3.5 wt.% chloride solution
E-mail:
In this study, the negatively charged graphene oxide (GO) nanosheets were modified with polyaniline (PAni) nanofibers and zinc cations through a layer-by-layer assembly method. The structure, morphology and thermal behavior of GO, GO-PAni and GO-PAni-Zn were characterized. The active corrosion inhibition performance of GO-PAni-Zn nanocomposite was demonstrated by electrochemical impedance spectroscopy (EIS) and polarization tests. The results confirmed high cation exchange capability and better anti-corrosion properties of GO-PAni-Zn sample than others. The theoretical outcomes derived from quantum mechanics computations revealed that inorganic zinc cations demonstrated electrostatic and cation-p interactions with emeraldine, implying the zinc propensity to bind to PAni Chains.
  1. Zaman I, Phan TT, Kuan HC, Meng QS, La LTB, Luong L, Youssf O, Ma J, Polymer, 52(7), 1603 (2011)
  2. Matin E, Attar M, Ramezanzadeh B, Prog. Org. Coat., 78, 395 (2015)
  3. Wan YJ, Tang LC, Gong LX, Yan D, Li YB, Wu LB, Jiang JX, Lai GQ, Carbon, 69, 467 (2014)
  4. Yi H, Chen C, Zhong F, Xu Z, High Perform. Polym., 26, 255 (2014)
  5. Palimi M, Rostami M, Mahdavian M, Ramezanzadeh B, J. Coat. Technol. Res., 12, 277 (2015)
  6. Ramezanzadeh B, Attar MM, Mater. Chem. Phys., 130(3), 1208 (2011)
  7. Ramezanzadeh B, Attar M, Prog. Org. Coat., 71, 314 (2011)
  8. Ramezanzadeh B, Attar M, Farzam M, Prog. Org. Coat., 72, 410 (2011)
  9. Ramezanzadeh B, Niroumandrad S, Ahmadi A, Mahdavian M, Moghadam MM, Corrosion Sci., 103, 283 (2016)
  10. Ramezanzadeh B., Haeri Z., Ramezanzadeh M., Chem. Eng. J., 303, 511 (2016)
  11. Ramezanzadeh B, Ghasemi E, Mahdavian M, Changizi E, Moghadam MM, Carbon, 93, 555 (2015)
  12. Yu ZX, Di HH, Ma Y, Lv L, Pan Y, Zhang CL, He Y, Appl. Surf. Sci., 351, 986 (2015)
  13. Sambyal P, Ruhi G, Dhawan R, Dhawan SK, Surf. Coat. Technol., 303, 362 (2016)
  14. Sababi M, Pan J, Augustsson PE, Sundell PE, Claesson PM, Corrosion Sci., 84, 189 (2014)
  15. Armelin E, Aleman C, Iribarren JI, Prog. Org. Coat., 65, 88 (2009)
  16. Hu XB, Yu Y, Wang YQ, Zhou JE, Song L, Appl. Surf. Sci., 329, 83 (2015)
  17. Hu XB, Yu Y, Hou WM, Zhou JE, Song LX, Appl. Surf. Sci., 273, 118 (2013)
  18. Schniepp HC, Li JL, McAllister MJ, Sai H, Herrera-Alonso M, Adamson DH, Prud'homme RK, Car R, Saville DA, Aksay IA, J. Phys. Chem. B, 110(17), 8535 (2006)
  19. Bhanvase B, Patel M, Sonawane S, Corrosion Sci., 88, 170 (2014)
  20. Petrova JN, Romanova JR, Madjarova GK, Ivanova AN, Tadjer AV, J. Phys. Chem. B, 115(14), 3765 (2011)
  21. Zhao Y, Schultz NE, Truhlar DG, J. Chem. Theory Comput., 2, 364 (2006)
  22. Miraftab R, Karimi B, Bahlakeh G, Ramezanzadeh B, J. Ind. Eng. Chem., 53, 348 (2017)
  23. Baldissera AF, Ferreira CA, Prog. Org. Coat., 75, 241 (2012)
  24. Campos M, Thiago AS, Appl. Polym. Sci., 40688, 1 (2014)
  25. Mostafaei A, Nasirpouri F, Org. Coat., 77, 146 (2014)
  26. Salehi E, Naderi R, Ramezanzadeh B, Appl. Surf. Sci., 396, 1499 (2017)
  27. Le DD, Nguyen TN, Nanosci. Nanotechnol., 7, 025002 (2016)
  28. Yeong C, Bae JH, Kim TY, Chang SH, Kim Y, Composites A, 75, 11 (2015)
  29. Kou L, Gao C, Nanoscale, 3, 519 (2011)
  30. Liu Y, J. Mater. Chem., 22, 13619 (2012)
  31. Tian Z, Yu H, RSC Adv., 4, 28195 (2014)