화학공학소재연구정보센터
Applied Catalysis A: General, Vol.552, 98-104, 2018
Oxidation of aromatic oxygenates for the production of terephthalic acid
We study the production of terephthalic acid (TA) from biomass-derived aromatic oxygenates. Among several heterogeneous catalysts tested, a carbon-supported Ir catalyst in 4-heptanone solvent gives the best TA yield from 1,4-dihydroxymethylbenzene. A maximum 76% TA yield is achieved at 100 degrees C and 12 bar O-2. Based on kinetic measurements, we show that the reaction progresses in two distinct pathways. First, the alcohol groups of the substrate are converted to the aldehydes via an O-assisted dehydrogenation pathway over Ir, and then the aldehydes are oxidized to the acid in the solution via a free radical mechanism. We demonstrate that it is easier to oxidize aromatic diols than p-xylene over a heterogeneous catalyst, and thus, the biomass route to TA may be an attractive alternative to the commercial crude oil-based process.