화학공학소재연구정보센터
Macromolecular Research, Vol.26, No.4, 353-358, April, 2018
Magnetite Embedded Mini-Emulsion Polymerized Polystyrene Particles and Their Magnetorheology
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Novel Fe3O4-encapsulated polystyrene (PS) hybrid particles were synthesized by a new preparation route involving mini-emulsion polymerization. A ferrofluid of oleic acid-coated Fe3O4 in octane was obtained initially, and then emulsified by an ultra-sonication process with sodium dodecyl sulfate as a surfactant. The suspension composed of the obtained Fe3O4 clusters was mixed with a styrene monomer, and the resulting Fe3O4 clusters served as templates for mini-emulsion polymerization. The embedded structure and uniform size of the fabricated Fe3O4/PS particles were examined by transmission electron microscopy, while their thermal properties, chemical structure, and magnetic properties were confirmed by thermogravimetric analysis, Fourier transform infrared spectroscopy, and vibrating sample magnetometry, respectively. The magnetorheological (MR) characteristics of the resulting particles dispersed in silicone oil were tested using a rotational rheometer. The fluid composed of Fe3O4/PS particles exhibited typical MR fluid behavior under applied magnetic fields.
  1. de Vicente J, Klingenberg DJ, Hidalgo-Alvarez R, Soft Matter, 7, 3701 (2012)
  2. Fang FF, Choi HJ, Seo Y, ACS Appl. Mater. Interfaces, 2, 54 (2010)
  3. Wu X, Xiao X, Tian Z, Jian W, J. Magn., 21, 244 (2016)
  4. Bombard AJF, Goncalves FR, Morillas JR, de Vicente J, Smart Mater. Struct., 23, 125013 (2014)
  5. Bossis G, Volkova O, Lacis S, Meunier A, Ferrofluids, 594, 202 (2002)
  6. Bica I, Choi HJ, Int. J. Mod. Phys. B, 22, 5041 (2008)
  7. Viota JL, de Vicente J, Duran JDG, Delgado A, J. Colloid Interface Sci., 284(2), 527 (2005)
  8. Bombard AJF, Knobel M, Akantara MR, Int. J. Mod. Phys. B, 21, 4858 (2007)
  9. Trendler AM, Bose H, Int. J. Mod. Phys. B, 21, 4967 (2007)
  10. Poojary UR, Hegde S, Gangadharan KV, Korea-Australia Rheol. J., 28, 301 (2016)
  11. Sidpara A, Jain VK, Int. J. Mech. Sci., 56, 50 (2012)
  12. Yang TH, Kwon HJ, Lee SS, An J, Koo JH, Kim SY, Kwon DS, Actuators A, 163, 180 (2010)
  13. Shen R, Shafrir SN, Miao CL, Wang MM, Lambropoulos JC, Jacobs SD, Yang H, J. Colloid Interface Sci., 342(1), 49 (2010)
  14. Yang J, Sun S, Li W, Du H, Alici G, Nakano M, J. Intell. Mater. Syst. Struct., 26, 1811 (2015)
  15. Bose H, Ehrlich J, J. Intell. Mater. Syst. Struct., 23, 979 (2011)
  16. Tang X, Zhang X, Tao R, Rong Y, J. Appl. Phys., 87, 2634 (2000)
  17. Ulicny JC, Golden MA, Namuduri CS, Klingenberg DJ, J. Rheol., 49(1), 87 (2005)
  18. Samouhos S, McKinley G, J. Fluid Eng. Trans. ASME, 129, 429 (2007)
  19. Kanno H, Shimada K, Ogawa J, Inoue N, Int. J. Appl. Electromagn. Mech., 25, 109 (2007)
  20. Mrlik M, Ilcikova M, Sedlacik M, Mosnacek J, Peer P, Filip P, Colloid Polym. Sci., 292, 2137 (2014)
  21. Jiang WQ, Zhu H, Guo CY, Li JF, Xue Q, Feng JF, Gong XL, Polym. Int., 59, 879 (2010)
  22. Guo ZH, Henry LL, Palshin V, Podlaha EJ, J. Mater. Chem., 16, 1772 (2006)
  23. Ahmad H, Sharafat MK, Alam MA, Rahman MM, Tauer K, Minami H, Sultana MS, Das BK, Shabnam R, Macromol. Res., 25(7), 671 (2017)
  24. Kawashita M, Tanaka M, Kokubo T, Inoue Y, Yao T, Hamada S, Shinjo T, Biomaterials, 26, 2231 (2005)
  25. Moon JM, Kim BS, Choi YS, Lee JO, Nakahara T, Yoshinaga K, Macromol. Res., 18(8), 793 (2010)
  26. Montagne F, Mondain-Monval O, Pichot C, Elaissari A, J. Polym. Sci. A: Polym. Chem., 44(8), 2642 (2006)
  27. Lee H, Lee E, Kim DK, Jang NK, Jeong YY, Jon S, J. Am. Chem. Soc., 128(22), 7383 (2006)
  28. Ding XB, Sun ZH, Wan GX, Jiang YY, React. Funct. Polym., 38(1), 11 (1998)
  29. Yanase N, Noguchi H, Asakura H, Suzuta T, J. Appl. Polym. Sci., 50, 765 (1993)
  30. Wormuth K, J. Colloid Interface Sci., 241(2), 366 (2001)
  31. Ramirez LP, Landfester K, Macromol. Chem. Phys., 204, 22 (2003)
  32. Nakamae K, Tanigawa S, Tsujiguchi T, Okamoto S, Yamaguchi K, Colloids Surf. A: Physicochem. Eng. Asp., 80, 85 (1993)
  33. Lee J, Isobe T, Senna M, J. Colloid Interface Sci., 177(2), 490 (1996)
  34. Ramirez LP, Landfester K, Macromol. Chem. Phys., 204, 22 (2003)
  35. Gong T, Yang D, Hu JH, Yang WL, Wang CC, Lu JQ, Colloids Surf. A: Physicochem. Eng. Asp., 339, 232 (2009)
  36. Shen LF, Laibinis PE, Hatton TA, Langmuir, 15(2), 447 (1999)
  37. Ramirez LP, Landfester K, Macromol. Chem. Phys., 204, 22 (2003)
  38. Xu H, Cui LL, Tong NH, Gu HC, J. Am. Chem. Soc., 128(49), 15582 (2006)
  39. Shabnam R, Rahman MA, Miah MAJ, Sharafat MK, Islam HMT, Gafur MA, Ahmad H, Ind. Eng. Chem. Res., 56(27), 7747 (2017)
  40. Kim DN, Tian Y, Choi HJ, RSC Adv., 5, 81546 (2015)
  41. Wang H, Wang RX, Wang L, Tian XY, Colloids Surf. A: Physicochem. Eng. Asp., 384, 624 (2011)
  42. Hong R, Feng B, Liu G, Wang S, Li H, Ding J, Zheng Y, Wei D, J. Alloy. Compd., 476, 612 (2009)
  43. Hong CH, Liu YD, Choi HJ, Appl. Clay Sci., 80, 366 (2013)
  44. Hato MJ, Choi HJ, Sim HH, Park BO, Ray SS, Colloids Surf. A: Physicochem. Eng. Asp., 377, 103 (2011)
  45. Song KH, Park BJ, Choi HJ, IEEE Trans. Magn., 45, 4045 (2009)
  46. Rankin PJ, Horvath AT, Klingenberg DJ, Rheol. Acta, 38(5), 471 (1999)
  47. Parthasarathy M, Klingenberg DJ, Mater. Sci. Eng. R-Rep., 172, 57 (1996)
  48. Cho MS, Lim ST, Jang IB, Choi HJ, Jhon MS, IEEE Trans. Magn., 40, 3036 (2004)
  49. Bossis G, Lacis S, Meunier A, Volkova O, J. Magn. Magn. Mater., 252, 224 (2002)
  50. Parmar KPS, Meheust Y, Schjelderupsen B, Fossum JO, Langmuir, 24(5), 1814 (2008)
  51. Liu XH, Wong PL, Wang W, J. Intell. Mater. Syst. Struct., 21, 1193 (2010)