Starch composites and their reduction of air permeation for self-extinguishable paper

Kwang Se Lee; Chan Woo Park; Young-Sin Kim; Jong-Duk Kim

Macromolecular Research, Vol.25, No.11, 1085-1090, November, 2017

DOI10.1007/s13233-017-5162-1 Export Citation

Starch composites and their reduction of air permeation for self-extinguishable paper

Kwang Se Lee, Chan Woo Park, Young-Sin Kim¹, and Jong-Duk Kim^†

Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology (KAIST), 291 Daehak-ro, Yuseong-gu, Daejeon 34141, Korea
¹Analysis Research center, KT&G corporation, 30 Gajeong-ro, Yuseong-gu, Daejeon 34128, Korea

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A new approach to achieve a self-extinguishable property of paper (cellulosic fiber) based on biocompatible sources such as starch, a promising renewable material in the paper industry, is proposed. Hydrophilic α-waxy corn starch and hydrophobic aluminum octenyl succinate modified starch contributed to the selfextinguishable property by blocking the permeation of oxygen and covering the pores of the paper. By controlling the film density according to the size of the hydrophobic starch and the weight ratio of the hydrophobic/hydrophilic starch, the slurry mixture permeated the spacing between fibers. The type and weight ratio of starch affected the morphology, viscosity, and physical properties of the coating process and coated film. A mixed starch blend of 20 wt% hydrophilic starch and 10 wt% hydrophobic starch significantly retarded air permeation of the developed self-extinguishable paper.

Keywords:starch;particles;hydrophilic;hydrophobic;composite;permeation

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Shi YG, Seib PA, Carbohydr. Res., 227, 131 (1992)
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Matzinos P, Tserki V, Kontoyiannis A, Panayiotou C, Polym. Degrad. Stabil., 77, 17 (2002)
Wang SZ, Zhang L, Sun CL, Shao YL, Wu YZ, Lv JX, Hao XP, Adv. Mater., 28(19), 3768 (2016)
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