화학공학소재연구정보센터
Separation and Purification Technology, Vol.187, 233-243, 2017
Experimental simulation of continuous nanofiltration processes by means of a single module in batch mode
This work proposes a method of simulating the performance of continuous nanofiltration processes by means of experimental runs performed on a laboratory set-up equipped with a spiral-wound module working in batch recirculation mode. It describes how to implement the proper changes in feed concentration and operating conditions in a batch recirculated system in order to obtain similar conditions to those of a continuous one. The analogy between the concentration process in the continuous and in the batch recirculation system is discussed and the difference in ion concentration of the cumulative permeate between the two systems is estimated numerically. The procedure was applied in a case study to estimate the performance of a continuous process intended to remove nitrate from brackish water using a high rejection nanofiltration membrane (DowFilmtec NF90). The sequence of concentration steps performed in the batch-recirculated set-up yielded an estimation of the ion concentration profiles throughout the continuous system. A mathematical analysis of the results showed that the nitrate concentration in the permeate experimentally obtained in the batch system is 4.5% higher than that expected in the continuous system. The experimental method described here can be used to design membrane system applications for which the target ions are not accurately predicted by models or are not included in commercial software. (C) 2017 Published by Elsevier B.V.