Inorganic Chemistry, Vol.56, No.11, 6039-6043, 2017
Synthesis and Dual-Emission Feature of Salen-Al/Triarylborane Dyads
Novel salen-Al/triarylborane dyad complexes were prepared and characterized with their corresponding mononuclear compounds. The UV-vis and photoluminescence experiments for dyads exhibited photoinduced energy transfer from borane to the salen-Al moiety in an intramolecular manner. Theoretical calculation and fluoride titration results further supported these intramolecular energy-transfer features.