화학공학소재연구정보센터
Electrochimica Acta, Vol.241, 197-207, 2017
Enhanced Performance of Lithium Sulfur Batteries with Sulfur Embedded in Sm2O3-Doped Carbon Aerogel as Cathode Material
A Sm2O3 decorated carbon aerogel (CA-Sm) was successfully synthesized through a sol-gel from resorcinol, phloroglucinol (P), formaldehyde and catalyst of oxalic acid and doping compound with Sm2O3 strategies. The small amount of active reactant phloroglucinol promotes synthesis of carbon aerogel (CA) and formation of uniform and porous carbon spheres. The CA-Sm composites present an interlinked porous structure and high specific surface area. The CA-Sm with sulfur loading (CA/S-Sm) from the composite via molten sulfur technique exhibits an enhanced performance with long-term cycling stability and high rate capacity. In particular, the cathode of CA/S-Sm-2 with Sm/C molar ratio of 2/400 achieved a high initial discharge capacity of 1347 and 976 mAh g (1) at 0.2C and 2C, respectively. And the cathode exhibited a nice long-term cycling stability with a high initial discharge capacity of 1175 mAh g (1) and maintained 861 mAh g (1) after 300 cycles at 0.5C. The excellent electrochemical performance of the battery is attributed to interrelated nanospheres, porous carbon structure, large specific surface area of Sm2O3-doped CA composites and improved electronic and ionic transport at the cathode. (C) 2017 Elsevier Ltd. All rights reserved.