화학공학소재연구정보센터
Current Applied Physics, Vol.17, No.5, 774-780, 2017
Study of temperature-induced structural evolution in (Na0.5Bi0.5)TiO3-(K0.5Bi0.5)TiO3-(K0.5Na0.5)NbO3 lead-free ceramics
In this work, the temperature-induced structural evolution in 0.79(Na0.5Bi0.5)TiO3-0.2(K0.5Bi0.5)TiO3-0.01(K0.5Na0.5)NbO3 (NKBNT) lead-free ceramics was investigated by Raman microscopic spectroscopy combined with electrical macroscopic measurements. The NKBNT ceramics possess the local structure with the coexisted rhombohedral R3c and tetragonal P4bm polar-nano-regions (PNRs). The R3c and P4bm PNRs coexist in a wide temperature range, then the local structure transforms to the P4bm PNRs around the temperature of dielectric maximum (T-m) evidenced by the doublet splitting of Ti-O modes (peak B) and oxygen octahedral vibrational modes (peak C). The discontinuous changes of wavenumber and line-width of peak B-2 and peak C-3 as well as the dielectric local maxima around the rhombohedral-tetragonal phase transition temperature (T-RT) are considered to result from the thermal evolution of R3c and P4bm PNRs. The macroscopic changes of non-polar phase with electric field and temperature were investigated by the temperature-dependent polarization-electric field (P-E) loops, current-electric field (I-E) loops and bipolar strain (S-E) curves. The electric-field level necessary to form the long-range ferroelectric order from non-polar phase associated with the stability of the induced ferroelectric phase depends strongly on the temperature. (C) 2017 Elsevier B.V. All rights reserved.