화학공학소재연구정보센터
Catalysis Letters, Vol.147, No.6, 1392-1402, 2017
Dynamic Impact of RuCl3 Catalyst on the Oxidation of Cyclamate with Acidified Bromamine-T: Elucidation of Mechanistic Pathways and Kinetic Modeling
Oxidation-Kinetics of cyclamate by bromamine-T (BAT) in HClO4 medium catalyzed by RuCl3 exhibits a first-order dependence on [BAT](0), fractional-order on both [Cyclamate](0) and [RuCl3], and inverse fractional-order on [HClO4]. RuCl3 catalyst accelerated the reaction by a splendid 48 times. Plausible mechanism and related rate law have been deduced. The Stoichiometry of the reaction is:.