화학공학소재연구정보센터
International Journal of Hydrogen Energy, Vol.41, No.48, 22997-23006, 2016
The identification and characterization of Ptx-zn(1-x) photocatalysts for photoelectrochemical water splitting applications
A pico-liter dispensing system is used to fabricate Pt-x-Zn1-xO photocatalyst arrays on a FTO substrate. The photoelectrochemical performance of these arrays is determined quickly, using scanning electrochemical microscopy (SECM), where an optical fiber is connected to a xenon lamp. The spot for the Pt-0.2-Zn0.8O exhibits the highest photocurrent in 0.1 M Na2SO4/Na2SO3 solution, it is when irradiated by UV-visible light. This material is characterized using SEM, EDX, XRD, XPS, UV vis spectroscopy and Mott-Schottky analysis. The Pt-0.2-Zn0.8O photocatalyst is composed of a binary mixture of 84 mol% ZnO with a Wurtzite structure and 16 mol% Pt with a face center cubic structure. The photo electrochemical (PEC) properties of the bulk film photoelectrode confirm the SECM results. The superior photocatalytic activity of the Pt-0.2-Zn-0.8 O composite is mainly due to its high carrier density, which promotes the separation of photo-induced electrons and holes and gives a reduced probability of recombination. (C) 2016 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.