화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.46, 19-27, February, 2017
MnO2 nanorods grown NGNF nanocomposites for the application of highly sensitive and selective electrochemical detection of hydrogen peroxide
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The tetragonal a-phase structured manganese dioxide nanorods were densely grown over the nitrogen doped graphite nanofibers (NGNF/MnO2) via a facile and one-pot hydrothermal technique. The amperometric results depicted that NGNF/MnO2 composite exhibited a high sensitivity of 1096 mAmM-1 cm-2 and a wide linear range from 0.1 to 11 mM with the lower detection limit of 1.25 mMtoward the non-enzymatic hydrogen peroxide (H2O2) detection, owing to the synergistic effects of NGNF and MnO2. In the prospect of excellent selectivity, real sample analysis and other striking advantages, the developed non-enzymatic sensors hold promising potential for the tight monitoring of H2O2 in the food and clinical diagnosis fields.
  1. Lu CP, Lin CT, Chang CM, Wu SH, Lo LC, J. Agric. Food Chem., 59, 11403 (2011)
  2. Xu L, Zhang M, Hou Y, Huang W, Yao C, Wu Q, Anal. Methods, 7, 3480 (2015)
  3. Yu D, Wang P, Zhao Y, Fan A, Talanta, 146, 655 (2016)
  4. Wang J, Cao W, Niu F, J. Toxicol. Sci., 40, 585 (2015)
  5. Li J, Dasgupta PK, Anal. Chem., 72, 5338 (2000)
  6. Klassen NV, Marchington D, McGowan HCE, Anal. Chem., 66, 2921 (1994)
  7. Guo X, Wang Y, Wu F, Ni Y, Kokot S, Analyst, 140, 1119 (2015)
  8. Gimeno P, Bousquet C, Lassu N, Maggio AF, Civade C, Brenier C, Lempereur L, J. Pharm. Biomed. Anal., 107, 386 (2015)
  9. Zhang R, He S, Zhang C, Chen W, J. Mater. Chem. B, 3, 4146 (2015)
  10. Mahbub P, Zakaria P, Guijt R, Macka M, Dicinoski G, Breadmore M, Nesterenk PN, Talanta, 143, 191 (2015)
  11. Hoshino M, Kamino S, Doi M, Takada S, Mitani S, Yanagihara R, Asano M, Yamaguchi T, Fujita Y, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 117, 814 (2014)
  12. Tashkhourian J, Nezhad MRH, Khodaveisi J, Dashti R, Anal. Chim. Acta, 762, 87 (2013)
  13. Han TH, Khan MM, Lee J, Cho MH, J. Ind. Eng. Chem., 20(4), 2003 (2014)
  14. Ramachandran K, Kalpana D, Sathishkumar Y, Lee YS, Ravichandran K, Kumar GG, J. Ind. Eng. Chem., 35, 29 (2016)
  15. Khan SB, Asiri AM, Akhtar K, Rub MA, J. Ind. Eng. Chem., 30, 234 (2015)
  16. Ju J, Chen W, Anal. Chem., 87, 1903 (2015)
  17. Kim SH, Kim JJ, Suh SW, Park BK, Lee JB, J. Ind. Eng. Chem., 16(5), 741 (2010)
  18. Meng FH, Yan XL, Liu JG, Gu J, Zou ZG, Electrochim. Acta, 56(12), 4657 (2011)
  19. Yan Z, Zhao J, Qin L, Mu F, Wang P, Feng X, Microchim. Acta, 180, 145 (2013)
  20. Huang Y, Li SFY, J. Electroanal. Chem., 690, 8 (2013)
  21. Lu X, Xiao X, Li Z, Xu F, Tan H, Sun L, Wang L, Anal. Methods, 6, 235 (2014)
  22. Bai W, Zheng J, Sheng Q, Electroanalysis, 25, 2305 (2013)
  23. Park JH, Kang DC, Park SJ, Shin CH, J. Ind. Eng. Chem., 25, 250 (2015)
  24. Thiagarajan S, Tsai TH, Chen SM, Int. J. Electrochem. Sci., 6, 2235 (2011)
  25. McAuley CB, Shao L, Wildgoose GG, Green MLH, Compton RG, New J. Chem., 32, 1195 (2008)
  26. Kumar GG, Awan Z, Nahm KS, Xavier JS, Biosens. Bioelectron., 53, 528 (2014)
  27. Peera SG, Tintula KK, Sahu AK, Shanmugam S, Sridhar P, Pitchumani S, Electrochim. Acta, 108, 95 (2013)
  28. Shcherban ND, Filonenko SM, Yaremov PS, Skoryk M, Ilyin VG, Aho A, Murzin DY, J. Ind. Eng. Chem., 34, 292 (2016)
  29. Zahoor A, Christy M, Hwang YJ, Lim YR, Kim P, Nahm KS, Appl. Catal. B: Environ., 147, 633 (2014)
  30. Ramachandran K, Babu KJ, Kumar GG, Kim AR, Yoo DJ, Sci. Adv. Mater., 7, 329 (2015)
  31. Nan D, Huang ZH, Lv R, Yang L, Wang JG, Shen W, Lin Y, Yu X, Ye L, Sun H, Kang F, J. Mater. Chem. A, 2, 19678 (2014)
  32. Zahoor A, Jeon JS, Jang HS, Christy M, Hwang Y, Nahm KS, Sci. Adv. Mater., 6, 2712 (2014)
  33. Yuan D, Yuan X, Zou W, Zeng F, Huang X, Zhou S, J. Mater. Chem., 22, 17820 (2012)
  34. Zhang JX, Cao HQ, Tang XL, Fan WF, Peng GC, Qu MZ, J. Power Sources, 241, 619 (2013)
  35. Wang X, Li Y, Chem. Commun., 764 (2002)
  36. Li Z, Ding Y, Xiong Y, Yang Q, Xie Y, Chem. Commun., 918 (2005)
  37. Zhang C, Chen M, Xu X, Zhang L, Zhang L, Xia F, Li X, Liu Y, Hu W, Gao J, Nanotechnology, 25, 135707 (2014)
  38. Kaniyoor A, Jafri RI, Arockiadoss T, Ramaprabhu S, Nanoscale, 1, 382 (2009)
  39. Pham VH, Cuong TV, Hur SH, Oh E, Kim EJ, Shin EW, Chung JS, J. Mater. Chem., 21, 3371 (2011)
  40. Tang Z, Zhang L, Zeng C, Lin T, Guo B, Soft Matter, 8, 9214 (2012)
  41. Lei J, Lu X, Wang W, Bian X, Xue Y, Wang C, Li L, RSC Adv., 2, 2541 (2012)
  42. Wu P, Qian Y, Du P, Zhang H, Cai C, J. Mater. Chem., 22, 6402 (2012)
  43. Wu J, Wang Q, Umar A, Sun S, Huang L, Wang J, Gao Y, New J. Chem., 38, 4420 (2014)
  44. Li Y, Li XM, RSC Adv., 3, 2398 (2013)
  45. Sui N, Duan Y, Jiao X, Chen D, J. Phys. Chem. C, 113, 8560 (2009)
  46. Chauhan NPS, Mozafari M, Chundawat NS, Meghwal K, Ameta R, Ameta SC, J. Ind. Eng. Chem., 36, 13 (2016)
  47. Wang Y, Shao Y, Matson DW, Li J, Lin Y, ACS Nano, 4, 1790 (2010)
  48. Peera SG, Sahu AK, Bhata SD, Lee SC, RSC Adv., 4, 11080 (2014)
  49. Zhou Y, Neyerlin K, Olson TS, Pylypenko S, Bult J, Dinh HN, Gennett T, Shao Z, Hayre RO, Energy Environ. Sci., 3, 1437 (2010)
  50. Kondo T, Casolo S, Suzuki T, Shikano T, Sakurai M, Harada Y, Saito M, Oshima M, Trioni MI, Tantardini GF, Nakamura J, Phys. Rev. B, 86, 035436 (2012)
  51. Selvakumar K, Kumar SMS, Thangamuthu R, Ganesan K, Murugan P, Rajput P, Jha SN, Bhattacharyya D, J. Phys. Chem. C, 119, 6604 (2015)
  52. Shao YY, Sui JH, Yin GP, Gao YZ, Appl. Catal. B: Environ., 79(1-2), 89 (2008)
  53. Appavu B, Kannan K, Thiripuranthagan S, J. Ind. Eng. Chem., 36, 184 (2016)
  54. Raoof JB, Ojani R, Hasheminejad E, Rashid-Nadimi S, Appl. Surf. Sci., 258(7), 2788 (2012)
  55. Kannan PK, Rout CS, Chem.-Eur. J., 21, 9355 (2015)
  56. Sun Q, Park SJ, Kim S, J. Ind. Eng. Chem., 26, 265 (2015)
  57. Xiong R, Li X, Byeon A, Lee JW, RSC Adv., 3, 25752 (2013)
  58. Kondo T, Suzuk T, Nakamura J, J. Phys. Chem. Lett., 2, 577 (2011)
  59. Liu S, Yu B, Fei T, Zhang T, Sens. Actuators B-Chem., 201, 240 (2014)
  60. Tajabadi MT, Basirun WJ, Lorestani F, Zakaria R, Baradaran S, Amin YM, Mahmoudian MR, Rezayi M, Sookhakian M, Electrochim. Acta, 151, 126 (2015)
  61. Tian JQ, Liu S, Sun XP, Langmuir, 26(19), 15112 (2010)
  62. Li Z, Cui X, Zheng J, Wang Q, Lin Y, Anal. Chim. Acta, 597, 238 (2007)
  63. Scott CL, Zhao G, Pumera M, Electrochem. Commun., 12, 1788 (2010)
  64. Wu Y, Mao X, Cui X, Zhu L, Sens. Actuators B-Chem., 145, 749 (2010)
  65. Yang Y, Fu R, Wang H, Wang C, Microchim. Acta, 180, 1249 (2013)
  66. Tian Y, Wang FL, Liu YX, Pang F, Zhang X, Electrochim. Acta, 146, 646 (2014)
  67. Liu S, Tian JQ, Wang L, Li HL, Zhang YW, Sun XP, Macromolecules, 43(23), 10078 (2010)
  68. Jiang D, Zhang Y, Chu H, Liu J, Wan J, Chen M, RSC Adv., 4, 16163 (2014)
  69. Zhang R, Chen W, Sci. Bull., 60, 522 (2015)
  70. Liu S, Tian J, Wang L, Sun X, Carbon, 49, 3158 (2011)
  71. Kuo CC, Lan WJ, Chen CH, Nanoscale, 6, 334 (2014)
  72. Dong S, Xi J, Wu Y, Liu H, Fu C, Liu H, Xiao F, Anal. Chim. Acta, 853, 200 (2015)
  73. Liu M, Liu R, Chen W, Biosens. Bioelectron., 45, 206 (2013)
  74. Li L, Du Z, Liu S, Hao Q, Wang Y, Li Q, Wang T, Talanta, 82, 1637 (2010)
  75. Abdurhman AAM, Zhang Y, Zhang G, Wang S, Anal. Bioanal. Chem., 407, 8129 (2015)
  76. He S, Zhang B, Liu M, Chen W, RSC Adv., 4, 49315 (2014)
  77. Han Y, Zheng JB, Dong SY, Electrochim. Acta, 90, 35 (2013)
  78. Xiao XP, Song YH, Liu HY, Xie MY, Hou HQ, Wang L, Li Z, J. Mater. Sci., 48(14), 4843 (2013)
  79. Wang L, Deng M, Ding GH, Chen SH, Xu FG, Electrochim. Acta, 114, 416 (2013)