화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.45, 85-91, January, 2017
Synthesis, characterization and electrical studies of solid polymer electrolyte (1 - x) PANI-KAg4I5 · xAl2O3
E-mail:
In the present work, polymer composite solid electrolyte comprising of Polyaniline as polymer and KAg4I5 using Al2O3 of different compositions having the formula (1 - x) PANI-KAg4I5 · xAl2O3, x = 0.0-0.5 was prepared by solid state reaction method. The characterization was done by XRD, FTIR, TG-DTA, SEM and impedance spectroscopy. The thermal analysis and XRD confirms the presence of both AgI and KAg2I3 in the samples. The maximum conductivity was seen in the composition x = 0.4, i.e.1.84 × 10-2 S cm-1 at 313 K and 1.38 × 10-1 S cm-1 at 513 K, with an activation energy of 0.14 eV.
  1. Mindemark J, Sun B, Torma E, Brandell D, J. Power Sources, 298, 166 (2015)
  2. MacCallum JR, Vincent CA (Eds.), Polymer electrolyte reviews, vols. 1 and 2, Elsevier, London, 1987, p. 1989.
  3. Gray FM, Solid Polymer Electrolytes-Functional and Technological Applications, Wiley, Germany, 1991.
  4. Scrosati B, Application of Electroactive Polymers, Chapman and Hall, London, 1993.
  5. Kuo PL, Liang WJ, Chen TY, Polymer, 44(10), 2957 (2003)
  6. Neves S, Fonseca CP, J. Power Sources, 107(1), 13 (2002)
  7. Zhang G, Li X, Jia H, Pang X, Yang H, Wang Y, Ding K, Int. J. Electrochem. Sci., 7, 830 (2012)
  8. Bouridah A, Dalard F, Deroo D, Cheradame H, Lenest JF, Solid State Ion., 15, 233 (1985)
  9. Blonskyp M, Shriver DF, Austin P, Allcock HR, Am. Chem. Soc., 106, 6854 (1984)
  10. Kim YT, Smotkin ES, Solid State Ion., 149(1-2), 29 (2002)
  11. Yang XQ, Lee HS, Hanson L, Mcbreen J, Okamoto Y, J. Power Sources, 54, 198 (1995)
  12. Croce F, Appetecchi GB, Persi L, Scrosati B, Nature, 394, 456 (1998)
  13. Croce F, Persi L, Scrosati B, Serraino-Fiory F, Plichta E, Hendrickson MA, Electrochim. Acta, 46(16), 2457 (2001)
  14. Ding KQ, J. Chin. Chem. Soc., 56, 891 (2009)
  15. Kondawar SB, Deshpande MD, Agrawal SP, Int. J. Compos. Mater., 2, 32 (2012)
  16. Otero TF, Rodriguez J, Angulov E, Santamarias C, Synth. Met., 57, 3713 (1993)
  17. Pan W, Yang S, Li G, Jiang JM, Eur. Polym. J., 41, 2127 (2005)
  18. Panda M, Srinivas V, Thakur AK, Appl. Phys. Lett., 92, 132905 (2010)
  19. Park YH, Shin HC, Lee Y, Son Y, Baik DH, Macromolecules, 32(14), 4615 (1999)
  20. Park YH, Park CR, Synth. Met., 118, 187 (2001)
  21. Ram M, Choudhary RNP, Thakur AC, Mater. Chem. Phys., 101(2-3), 455 (2007)
  22. Dao LH, Leclerc M, Guay J, Chevalier JW, Synth. Met., 29, 377 (1989)
  23. Gupta N, Kumar D, Tomar SK, Int. J. Mater. Chem., 2, 79 (2012)
  24. Khiew PS, Huang NM, Radiman S, Ahmad MS, Mater. Lett., 58, 516 (2004)
  25. Kobayashi T, Yoneyama H, Tamura H, J. Electroanal. Chem., 161, 419 (1984)
  26. Kumar D, Chandra R, Indian J. Eng. Mater. Sci., 8, 209 (2001)
  27. Kumar D, Sharma RC, Eur. Polym. J., 34, 1053 (1998)
  28. Li XW, Wang GC, Li XX, Lu DM, Appl. Surf. Sci., 229(1-4), 395 (2004)
  29. Malmonge LF, Mattoso LH, Polymer, 36(2), 245 (1995)
  30. Mermillod M, Tanguy J, Petiot F, J. Electrochem. Soc., 133, 1073 (1986)
  31. Nalwa HS, Handbook of Organic Conductive Molecules and Polymer, vol. 2, Wiley, New York, 2006.
  32. Stephan AM, Nahm KS, Polymer, 47(16), 5952 (2006)
  33. Knauth P, J. Electroceram., 5, 111 (2000)
  34. Appetecchi GB, Scaccia S, Passerini S, J. Electrochem. Soc., 147(12), 4448 (2000)
  35. Bronstein LM, Karlinsey RL, Ritter K, Joo CG, Stein B, Zwanziger JW, J. Mater. Chem., 14, 1812 (2004)
  36. Itoh T, Miyamura Y, Iohikawa Y, Uno T, Kubo M, Yamamoto O, J. Power Sources, 119-121, 403 (2003)
  37. Kaarup SS, West K, Christiansen BZ, Solid State Ion., 28-30, 375 (1980)
  38. Wieczorek W, Mater. Sci. Eng. B-Solid State Mater. Adv. Technol., 15, 108 (1992)
  39. Capuoano F, Croce F, Scrosati B, J. Electrochem. Soc., 138, 1918 (1991)
  40. Boyce JB, Huberman BA, Phys. Rep. (Rev. Sect. Phys. Lett.), 51, 189 (1979)
  41. Shrishak K, Das E, SivaSankari P, Int. J. Eng. Res. Technol., ISSN:2278-0181., 2 (2013)
  42. Bradley JN, Greene PD, J. Chem. Soc.-Faraday Trans., 62, 2069 (1966)
  43. Brink C, Kores HAS, Acta Cryst., 5, 433 (1952)
  44. Hassan M, Al-hakimi AN, Arab. J. Chem., 4, 45 (2011)
  45. Khan MDA, Akhtar A, Nabi SA, New J. Chem., 39, 3728 (2015)
  46. Shao-Hua G, Yu-Xia W, Hong-Wei W, Shuai Y, Acta Phys. Sin., http://dx.doi.org/10.7498/aps.60.086601., 60, 086601 (2011)
  47. Evangelista JPC, Chellappa T, Coriolano ACF, Fernandes VJ, Souza LD, Araujo AS, Fuel Process. Technol., 104, 90 (2012)
  48. Trchov M, Stejskal J, Pure Appl. Chem., 83, 1803 (2011)
  49. Nadirnicherla R, Kalla R, Muchakayala R, Guo X, Solid State Ion., 278, 260 (2015)
  50. Ramesh S, Sominska E, Cina B, Chaim R, Gedanken A, J. Am. Ceram. Soc., 83(1), 89 (2000)
  51. Wang HK, Yi CY, Tian L, Wang WJ, Fang J, Zhao JH, Shen WG, J. Nanomater., Article ID 453915., 8 (2012)
  52. Iqbal MZ, Rafiuddin, Measurement, 81, 102 (2016)
  53. Asha, Goyal SL, Kumar D, Kumar S, Kishore N, Indian J. Pure Appl. Phys., 52, 341 (2014)
  54. Kulkarni VG, Campbell LD, Mathew WR, Synth. Met., 30, 321 (1989)
  55. Zhu YH, Liu EH, Luo ZY, Hu TT, Liu TT, Li ZP, Zhao QL, Electrochim. Acta, 118, 106 (2014)
  56. Wang QJ, Song WL, Fan LZ, Shi Q, J. Power Sources, 279, 405 (2015)
  57. Hassan M, Rafiuddin R, Res. Lett. Phys., Article ID 249402, 4 (2008)
  58. Iqbal MZ, Rafiuddin, Ceram. Int., 41, 13650 (2015)
  59. Orliukas AF, Kezionis A, Kazakevicius E, Solid State Ion., 176(25-28), 2037 (2005)
  60. Onwudiwe DC, Arfin T, Strydom CA, Electrochim. Acta, 127, 283 (2014)
  61. Lewandowski A, Zajder M, Frackowiak E, Beguin F, Electrochim. Acta, 46(18), 2777 (2001)
  62. Tallman DE, Levine KL, Siripirom C, Gelling VG, Bierwagen GP, Croll SG, Appl. Surf. Sci., 254(17), 5452 (2008)
  63. Garcia C, Franco JI, Tonazzi JCL, de Reca NEW, Solid State Ion., 9-10, 1233 (1983)
  64. Mentus SV, Susic MV, Gajinov SP, Solid State Ion., 11, 143 (1983)
  65. Solid Polymer Electrolytes: Inventors: Kim DW; Kim YR; Oh BK, all of Daejeon; Baek CW, Taeku, all of Rep. of Korea, Patent Number: 6,001,509, Date of Patent: December 14, 1999.
  66. Zhang T, Zeng Z, Huang H, Hing P, Kilner J, Mater. Lett., 57, 124 (2002)
  67. Xu HM, Yan HG, Chen ZH, Mater. Sci. Eng. B-Solid State Mater. Adv. Technol., 145, 85 (2007)
  68. Marrero-Jerez J, Nunez P, Frade JR, Solid State Ion., 256, 11 (2014)
  69. Dissanayake MAKL, Jayathilaka PARD, Bokalawala RSP, Albinsson I, Mellander BE, J. Power Sources, 119-121, 409 (2003)
  70. Kulasekarapandian K, Jayanthi S, Muthukumari A, Arulsankar A, Sundaresan B, Int. J. Eng. Res. Dev., 5, 30 (2013)
  71. Weston JE, Steele BCH, Solid State Ion., 7, 75 (1982)