Journal of Industrial and Engineering Chemistry, Vol.45, 85-91, January, 2017
Synthesis, characterization and electrical studies of solid polymer electrolyte (1 - x) PANI-KAg4I5 · xAl2O3
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In the present work, polymer composite solid electrolyte comprising of Polyaniline as polymer and KAg4I5 using Al2O3 of different compositions having the formula (1 - x) PANI-KAg4I5 · xAl2O3, x = 0.0-0.5 was prepared by solid state reaction method. The characterization was done by XRD, FTIR, TG-DTA, SEM and impedance spectroscopy. The thermal analysis and XRD confirms the presence of both AgI and KAg2I3 in the samples. The maximum conductivity was seen in the composition x = 0.4, i.e.1.84 × 10-2 S cm-1 at 313 K and 1.38 × 10-1 S cm-1 at 513 K, with an activation energy of 0.14 eV.
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