화학공학소재연구정보센터
Korean Journal of Chemical Engineering, Vol.33, No.12, 3359-3366, December, 2016
The effect of promoters on the CO2 reforming activity and coke formation of nanocrystalline Ni/Al2O3 catalysts prepared by microemulsion method
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Mesoporous nanocrystalline nickel-alumina promoted catalysts with high surface area were prepared by microemulsion (ME) method and employed in dry reforming of methane reaction. The catalysts were characterized by X-ray diffraction (XRD), Brunauer-Emmett-Teller surface area analysis (BET), temperature programmed reduction (TPR) and temperature programmed oxidation (TPO) techniques. The results showed that the prepared catalysts had high porosity with great surface area and small crystallite size. Among the K2O, MgO, CaO and BaO promoters, the MgO promoter showed considerable effect on catalytic performance and coke suppression of catalyst.
  1. Gaddalla AM, Sommer ME, Chem. Eng. Sci., 44, 2825 (1989)
  2. San-Jose-Alonso D, Juan-Juan J, Illan-Gomez MJ, Roman-Martinez MC, Appl. Catal. A: Gen., 371(1-2), 54 (2009)
  3. Delmon B, Appl. Catal. B: Environ., 1, 139 (1992)
  4. Chen W, Zhao GF, Xue QS, Chen L, Lu Y, Appl. Catal. B: Environ., 136, 260 (2013)
  5. Asencios YJO, Assaf EM, Fuel Process. Technol., 106, 247 (2013)
  6. Jose-Alonso DS, Illan-Gomez MJ, Roman-Martinez MC, Int. J. Hydrog. Energy, 38(5), 2230 (2013)
  7. Bychkov VY, Tyulenin YP, Firsova AA, Shafranovsky EA, Gorenberg AY, Korchak VN, Appl. Catal. A: Gen., 453, 71 (2013)
  8. Arandiyan H, Peng Y, Liu CX, Chang HZ, Li JH, J. Chem. Technol. Biotechnol., 89(3), 372 (2014)
  9. Zhu JQ, Peng XX, Yao L, Shen J, Tong DM, Hu CW, Int. J. Hydrog. Energy, 36(12), 7094 (2011)
  10. Arandiyan H, Li J, Ma L, Hashemnejad SM, Mirzaei MZ, Chen J, Chang H, Liu C, Wang C, Chen L, J. Ind. Eng. Chem., 18(6), 2103 (2012)
  11. Majidian N, Habibi N, Rezaei M, Korean J. Chem. Eng., 31(7), 1162 (2014)
  12. Kim J, Kim T, Yoo JW, Lee KB, Hong SI, Korean J. Chem. Eng., 29(10), 1329 (2012)
  13. Rezaei M, Alavi SM, Sahebdelfar S, Yan ZF, Energy Fuels, 22(4), 2195 (2008)
  14. Bradford MCJ, Vannice MA, Catal. Rev.-Sci. Eng., 41(1), 1 (1999)
  15. Ping C, Zhao-Yin H, Xiao-Ming Z, Chin. J. Chem., 23, 847 (2005)
  16. de Sousa HSA, da Silva AN, Castro AJR, Campos A, Filho JM, Oliveira AC, Int. J. Hydrog. Energy, 37(17), 12281 (2012)
  17. Shen WH, Momoi H, Komatsubara K, Saito T, Yoshida A, Naito S, Catal. Today, 171(1), 150 (2011)
  18. Hu YH, Ruckenstein E, Adv. Catal., 48, 297 (2004)
  19. Coleman LJI, Epling W, Hudgins RR, Croiset E, Appl. Catal. A: Gen., 363(1-2), 52 (2009)
  20. Boutonnet M, Kizling J, Stenius P, Maire G, Colloids Surf., 5, 209 (1982)
  21. Goula MA, Charisiou ND, Papageridis KN, Delimitis A, Pachatouridou E, Iliopoulou EF, Int. J. Hydrog. Energy, 40(30), 9183 (2015)
  22. Shiraz MHA, Rezaei M, Meshkani F, Can. J. Chem. Eng., 94(6), 1177 (2016)
  23. Roh HS, Jun KW, Catal. Surv. Asia, 12, 239 (2008)
  24. Zhong G, Angew. Chem.-Int. Edit., 42, 4247 (2003)
  25. Wang SB, Lu GQM, J. Chem. Technol. Biotechnol., 75(7), 589 (2000)
  26. Garcia-Dieguez M, Herrera C, Larrubia MA, Alemany LJ, Catal. Today, 197(1), 50 (2012)
  27. Yamazaki O, Nozaki T, Omata K, Fujimoto K, Chem. Lett., 1953 (1992)
  28. Wang YH, Liu HM, Xu BQ, J. Mol. Catal. A-Chem., 299(1-2), 44 (2009)
  29. Zhao A, Ying W, Zhang H, Ma H, Fang D, Catal. Commun., 17, 34 (2012)
  30. Eriksson S, Nylen U, Rojas S, Boutonnet M, Appl. Catal. A: Gen., 265(2), 207 (2004)
  31. Xu S, Zhao R, Wang XL, Fuel Process. Technol., 86(2), 123 (2004)
  32. Sutthiumporn K, Kawi S, Int. J. Hydrog. Energy, 36(22), 14435 (2011)
  33. Kang KM, Kim HW, Shim IW, Kwak HY, Fuel Process. Technol., 92(6), 1236 (2011)
  34. Bradford MCJ, Vannice MA, Catal. Rev.-Sci. Eng., 41(1), 1 (1999)
  35. Kim GJ, Cho DS, Kim KH, Kim JH, Catal. Lett., 28(1), 41 (1994)
  36. Wang SB, Lu GQ, Ind. Eng. Chem. Res., 38(7), 2615 (1999)
  37. Zhang ZL, Verykios XE, Macdonald SM, Affrossman S, J. Phys. Chem., 100(2), 744 (1996)