화학공학소재연구정보센터
Journal of Power Sources, Vol.326, 498-504, 2016
Binder-free flexible LiMn2O4/carbon nanotube network as high power cathode for rechargeable hybrid aqueous battery
Highly flexible LiMn2O4/carbon nanotube (CNT) electrodes are developed and used as a high power cathode for the Rechargeable Hybrid Aqueous Battery (ReHAB). LiMn2O4 particles are entangled into CNT networks, forming a self-supported free-standing hybrid films. Such hybrid films can be used as electrodes of ARLB without using any additional binders. The binder-free LiMn2O4/CNT electrode exhibits good mechanical properties, high conductivity, and effective charge transport. High-rate capability and high cycling stability are obtained. Typically, the LiMn2O4/CNT electrode achieves a discharge capacity of 72 mAh g(-1) at the large-current of 20 C (1 C = 120 mAh g(-1)), and exhibits good cycling performance and high reversibility: Coulombic efficiency of almost 100% over 300 charge-discharge cycles at 4 C. By reducing the weight, and improving the large-current rate capability simultaneously, the LiMn2O4/CNT electrode can highly enhance the energy/power density of ARLB and hold potential to be used in ultrathin, lightweight electronic devices. (C) 2016 Elsevier B.V. All rights reserved.