화학공학소재연구정보센터
Journal of Colloid and Interface Science, Vol.478, 288-295, 2016
Effects of single- and multi-organic acid ligands on adsorption of copper by Fe3O4/graphene oxide-supported DCTA
The Fe3O4/graphene oxide-supported 1,2-diaminocyclohexanetetraacetic acid composite (Fe3O4/GO/DCTA) was used as an adsorbent for Cu(II) removal. The effects of six organic acid ligands (formate, acetate, benzoate, oxalate, tartrate, and edetate) on the adsorption process were investigated in single- and multi-ligand systems. The results demonstrated that the adsorption processes were affected by solution pH and ionic strength. The experimental data of kinetics and isotherm followed the pseudo-second-order model and the Langmuir model, respectively. In the single-ligand systems, the presence of formate, acetate, and benzoate slightly altered the Cu(II) adsorption property, while the adsorption processes were significantly affected by the oxalate, tartrate, and edetate ligands. In the multi-ligand systems, the Cu(II) adsorption was influenced by the type and concentration of organic acid ligands. The sequence of the main effect was found to be: edetate > oxalate > benzoate > formate > tartrate > acetate, and the sequence of the two-factor interaction effect was found to be: AE (formate x tartrate) > BF (acetate x edetate) > AF (formate x edetate) > BD (acetate x oxalate) > AC (formate x benzoate) > AD (formate x oxalate) > AB (formate x acetate). (C) 2016 Published by Elsevier Inc.